ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 19, Problem 19.34P
Interpretation Introduction

Interpretation:

The structures of all aldehydes or ketones that result in the formation of 1-isobutyl-4-methylbenzene after application of either the Wolff-Kishner or Clemmensen reduction are to be stated.

Concept introduction:

The organic reaction which is used for the preparation of an alkane from an aldehyde or ketone using reagent H2NNH2 in the presence of base (OH) is called Wolff-Kishner reduction reaction. The major product of the reaction is present in maximum yield as compared to the other.

The organic reaction used for the conversion of an aldehyde or ketone to an alkane using reagent Zn(Hg) in the presence of HCl in concentrated form is called Clemmensen reduction reaction.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 19 Solutions

ORGANIC CHEM +SG +SAPLING >IP<

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