ORGANIC CHEM +SG +SAPLING >IP<
ORGANIC CHEM +SG +SAPLING >IP<
6th Edition
ISBN: 9781319171179
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 19, Problem 19.12P
Interpretation Introduction

(a)

Interpretation:

SN1 mechanism for the solvolysis of CH3OCH2Cl in ethanol with appropriate resonance structures for the carbocation intermediate is to be drawn.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. It is of two types, SN1 and SN2.

The SN2 reaction is a nucleophilic substitution bimolecular single-step reaction in which the addition of nucleophile and removal of leaving group takes place simultaneously.

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the alkyl halide in part (a) undergoes solvolysis much more rapidly as compared to 1 chlorobutane is to be stated.

Concept introduction:

The nucleophilic substitution reactions are the reactions in which one nucleophile is substituted by another nucleophile. These reactions depend upon the nucleophilicity and concentration of the nucleophile. It is of two types, SN1 and SN2.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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Chapter 19 Solutions

ORGANIC CHEM +SG +SAPLING >IP<

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