(a) Interpretation: A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated. Concept introduction: The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

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Answer 1

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Answer 3

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Answer 4

Question

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

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Answer 5

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

Answer 6

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Answer 7

Chapter 19, Problem 19.15P

Interpretation Introduction

(a)

Interpretation:

A curved-arrow mechanism corresponding to the hydroxide-catalyzed hydration of acetaldehyde is to be stated.

Concept introduction:

The chemical reaction in which a reactant combines with water molecule is known as hydration reaction. The addition of water with an unsaturated compound takes place to form a hydrated compound.

Answer 8

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

A curved-arrow mechanism corresponding to the decomposition of acetone cyanohydrin in aqueous hydroxide is to be stated. The reason as to why the ketone-cyanohydrin equilibrium favors the ketone at high pH is to be stated.

Concept introduction:

A chemical reaction in which a reactant breaks down to generate at least two products is known as decomposition reaction. The involvement of an energy source like heat also takes place in decomposition reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19 - Prob. 19.1P Ch. 19 - Prob. 19.2P Ch. 19 - Prob. 19.3P Ch. 19 - Prob. 19.4P Ch. 19 - Prob. 19.5P Ch. 19 - Prob. 19.6P Ch. 19 - Prob. 19.7P Ch. 19 - Prob. 19.8P Ch. 19 - Prob. 19.9P Ch. 19 - Prob. 19.10P

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Chapter 19 Solutions