Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 19, Problem 19.30P
Draw the structures and give the IUPAC names for the carboxylic acids having molecular formula
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Draw the structures and give the IUPAC names for the carboxylic acids having molecular formula C3H1,02. Then give the IUPAC
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Chapter 19 Solutions
Organic Chemistry
Ch. 19 - Give the IUPAC name for each compound.Ch. 19 - Problem 19.2 Give the structure corresponding to...Ch. 19 - Problem 19.3 Draw the structure corresponding to...Ch. 19 - Prob. 19.4PCh. 19 - Prob. 19.5PCh. 19 - Rank the following compounds in order of...Ch. 19 - Explain how you could use IR spectroscopy to...Ch. 19 - Identify the structure of a compound of molecular...Ch. 19 - Problem 19.9 How many tetrahedral stereogenic...Ch. 19 - What alcohol can be oxidized to each carboxylic...
Ch. 19 - Prob. 19.11PCh. 19 - Draw the products of each acid-base reaction.Ch. 19 - Problem 19.14 Given the values in Appendix A,...Ch. 19 - Problem 19.15 Rank the labeled protons in...Ch. 19 - Problem 19.16 Match each of the following values ...Ch. 19 - Rank the compounds in each group in order of...Ch. 19 - Rank the compounds in each group in order of...Ch. 19 - Prob. 19.18PCh. 19 - Which of the following pairs of compounds can be...Ch. 19 - Problem 19.21 Two other commonly used sulfonic...Ch. 19 - Problem 19.22 Draw both enantiomers of each amino...Ch. 19 - Problem 19.23 Explain why amino acids, unlike most...Ch. 19 - Problem 19.24 Draw the positively charged,...Ch. 19 - Prob. 19.24PCh. 19 - Problem 19.26 Explain why the of the group of...Ch. 19 - Answer each question for A and B depicted in the...Ch. 19 - Prob. 19.27PCh. 19 - Give the IUPAC name for each compound. a....Ch. 19 - Prob. 19.29PCh. 19 - Draw the structures and give the IUPAC names for...Ch. 19 - Prob. 19.31PCh. 19 - Rank the compounds in each group in order of...Ch. 19 - 19.33 Draw the organic products formed in each...Ch. 19 - 19.34 Identify the lettered compounds in each...Ch. 19 - 19.35 Using the table in Appendix A, determine...Ch. 19 - Draw the products of each acid-base reaction, and...Ch. 19 - Which compound in each pair has the lower pKa?...Ch. 19 - 19.38 Rank the compounds in each group in order of...Ch. 19 - Rank the compounds in each group in order of...Ch. 19 - 19.40 Match the values to the appropriate...Ch. 19 - Prob. 19.41PCh. 19 - 19.42 Which carboxylic acid has the lower ,...Ch. 19 - Prob. 19.43PCh. 19 - 19.44 Explain the following statement. Although...Ch. 19 - Prob. 19.45PCh. 19 - 19.46 Explain why the of compound A is lower than...Ch. 19 - 19.47 Rank the following compounds in order of...Ch. 19 - Explain the following result. Acetic acid...Ch. 19 - 19.50 Draw all resonance structures of the...Ch. 19 - As we will see in Chapter 23, CH bonds are...Ch. 19 - Prob. 19.51PCh. 19 - The pKa of acetamide (CH3CONH2) is 16. Draw the...Ch. 19 - 19.54 Write out the steps needed to separate...Ch. 19 - Prob. 19.54PCh. 19 - Can octane and octan -1- ol be separated using an...Ch. 19 - 19.57 Identify each compound from its spectral...Ch. 19 - 19.58 Use the NMR and IR spectra given below to...Ch. 19 - 19.59 An unknown compound (molecular formula )...Ch. 19 - 19.60 Propose a structure for (molecular formula...Ch. 19 - Prob. 19.60PCh. 19 - 19.61 Match the data to the appropriate...Ch. 19 - Prob. 19.62PCh. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - 19.65 For each amino acid ,draw its neutral,...Ch. 19 - Calculate the isoelectric point for each amino...Ch. 19 - 19.67 Lysine and tryptophan are two amino acids...Ch. 19 - Prob. 19.68PCh. 19 - Prob. 19.69PCh. 19 - Prob. 19.70PCh. 19 - Prob. 19.71PCh. 19 - 19.71 Hydroxy butanedioic acid occurs naturally in...Ch. 19 - 19.72 Although it was initially sold as a rat...
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- What is the correct IUPAC name of the given structure? Br OH CH3 CH3 What is the name of the compound produced by the reaction of benzoic acid with potassium hydroxide? What is the IUPAC name of the ester formed by the reaction of CH3COOH and CH3CH2CH2OH? Which of these products would be formed in the following reaction? H2O NaOH O 1-propanol and butanoic acid O 1-propanol and sodium butanoate O 1-butanol and propanoic acid 1-butanol and sodium propanoatearrow_forwardWrite the chemical equation for a pentanoate ion acting as base when it reacts with hydrochloric acid (HCI). Which is formula of this rule of reaction?arrow_forwardDraw the structure for the carboxylic acid formed by the mild oxidation of 2-propanone.arrow_forward
- Draw the structures for the four carboxylic acids of molecular formula C 5H 10O 2. Give the IUPAC name for each compound.arrow_forwardName: 2) When water is introduced into an ester under high temperature conditions, esters are hydrolyzed into their carboxylic acid and alcohol components. Draw the structure of the resulting carboxylic acid and alcohol when the ester shown below is hydrolyzed. + H20 3) Why is it important that the test tube be thoroughly dry before making esters? Use the principles of chemical equilibrium to explain your answer.arrow_forwardPhenols are aromatic rings with an alcohol functional group attached directly to the ring. These compounds have unique acidity and solubility for alcohol groups. Predict the solubility of this phenol in water.arrow_forward
- Describe the acidity of different carboxylic acids and predict the products obtained when they react with strong bases.arrow_forwardWrite the chemical equation for the decarboxylation of 2-methyl-propanoic acid. Which is formula of this rule of reaction?arrow_forwardWhich reagent describe the following reaction? Ester Carboxylic acid or Carboxylate: which is the conjugate base of carboxylic acid Alcohol Amine Acid Halide Amide Anhydridearrow_forward
- Which of the following is not true about low molar mass carboxylic acids? They have a sour taste. They change red litmus to blue. They form aqueous solutions with a pH less than 7. They react with bases to form water and a salt. Which of the following statements best describes the solubility of aliphatic carboxylic acids in water? The solubility decreases as the number of carbon atoms increase. The fist 4-carbon acids are miscible with water, while those with 8 or more carbons are insoluble. The solubility increases as the number of carbon atoms decrease. All of them are soluble in water. What is the order of increasing acidity for the following compounds? (least to most) COOH COOH COOH COOH CH3 NO₂ I III IV IV, I, III, II III, II, I, IV II, III, I, IV III, II, IV, I IIarrow_forwardWhen the ester ethyl butanoate, CH;CH2CH,COOCH,CH3, is hydrolyzed under basic conditions, which compounds are the products? O ethyl alcohol and butanoic acid O butanol and cthanoic (acetic) acid O ethyl alcohol and the butanoate lon O butanol and the ethanoatc ionarrow_forwardwhy n-hexanol has higher boiling point than n-hexane. why acetic acid is more acidic then butanoic acid. why sugar is soluble in water in terms of their molecular interactions.arrow_forward
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