Organic Chemistry
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 19, Problem 19.1P

Give the IUPAC name for each compound.

Chapter 19, Problem 19.1P, Give the IUPAC name for each compound.

Expert Solution
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Interpretation Introduction

(a)

Interpretation:

The IUPAC name for the given compound is to be stated.

Concept introduction:

The chemical structures are described by IUPAC name or common names. IUPAC nameis different from common names because IUPAC nameis applied at international level and it comprises suffix, prefix, numbers and other priority rules.

Answer to Problem 19.1P

The IUPAC name of the compound is 3,3dimethylhexanoicacid.

Explanation of Solution

The numbering of carbon atoms in the given compound is shown below.

Organic Chemistry, Chapter 19, Problem 19.1P , additional homework tip  1

Figure 1

The given compound has a chain of six carbon atoms. The carboxylic acid is present as a functional group in the compound. Two methyl groups are present at a third carbon atom. Therefore, the name of the compound is 3,3dimethylhexanoicacid.

Conclusion

The IUPAC name of the given compound is 3,3dimethylhexanoicacid.

Expert Solution
Check Mark
Interpretation Introduction

(b)

Interpretation:

The IUPAC name for the given compound is to be stated.

Concept introduction:

The chemical structures are described by IUPAC name or common names. IUPAC name is different from common names because IUPAC name is applied at international level and it comprises suffix, prefix, numbers and other priority rules.

Answer to Problem 19.1P

The IUPAC name of the compound is 3bromo4chloro2fluoropentanoicacid.

Explanation of Solution

The numbering of carbon atoms in the given compound is shown below.

Organic Chemistry, Chapter 19, Problem 19.1P , additional homework tip  2

Figure 2

The given compound has a chain of five carbon atoms. The carboxylic acid is present as a functional group in the compound. Fluorine, chlorine and bromine is present at second, third and fourth carbon atoms respectively. Therefore, the name of the compound is 3bromo4chloro2fluoropentanoicacid.

Conclusion

The IUPAC name of the compound is 3bromo4chloro2fluoropentanoicacid.

Expert Solution
Check Mark
Interpretation Introduction

(c)

Interpretation:

The IUPAC name for the given compound is to be stated.

Concept introduction:

The chemical structures are described by IUPAC name or common names. IUPAC name is different from common names because IUPAC name is applied at international level and it comprises suffix, prefix, numbers and other priority rules.

Answer to Problem 19.1P

The IUPAC name of the compound is 2, 4-diethylhexanoicacid.

Explanation of Solution

The numbering of carbon atoms in the given compound is shown below.

Organic Chemistry, Chapter 19, Problem 19.1P , additional homework tip  3

Figure 3

The given compound has a chain of six carbon atoms. The carboxylic acid is present as a functional group in the compound. Two ethyl groups are present at second and fourth carbon atoms. Therefore, the name of the compound is 2, 4-diethylhexanoicacid.

Conclusion

The IUPAC name of the compound is 2, 4-diethylhexanoicacid.

Expert Solution
Check Mark
Interpretation Introduction

(d)

Interpretation:

The IUPAC name for the given compound is to be stated.

Concept introduction:

The chemical structures are described by IUPAC name or common names. IUPAC name is different from common names because IUPAC name is applied at international level and it comprises suffix, prefix, numbers and other priority rules.

Answer to Problem 19.1P

The IUPAC name of the compound is 4isopropyl6,8dimethylnonanoicacid.

Explanation of Solution

The numbering of carbon atoms in the given compound is shown below.

Organic Chemistry, Chapter 19, Problem 19.1P , additional homework tip  4

Figure 4

The given compound has a chain of nine carbon atoms. The carboxylic acid is present as a functional group in the compound. Two methyl groups are present at eighth and nine carbon atoms, while one isopropyl group is present at fourth carbon. Therefore, the name of the compound is 4isopropyl6,8dimethylnonanoicacid.

Conclusion

The IUPAC name of the compound is 4isopropyl6,8dimethylnonanoicacid.

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Chapter 19 Solutions

Organic Chemistry

Ch. 19 - Prob. 19.11PCh. 19 - Draw the products of each acid-base reaction.Ch. 19 - Problem 19.14 Given the values in Appendix A,...Ch. 19 - Problem 19.15 Rank the labeled protons in...Ch. 19 - Problem 19.16 Match each of the following values ...Ch. 19 - Rank the compounds in each group in order of...Ch. 19 - Rank the compounds in each group in order of...Ch. 19 - Prob. 19.18PCh. 19 - Which of the following pairs of compounds can be...Ch. 19 - Problem 19.21 Two other commonly used sulfonic...Ch. 19 - Problem 19.22 Draw both enantiomers of each amino...Ch. 19 - Problem 19.23 Explain why amino acids, unlike most...Ch. 19 - Problem 19.24 Draw the positively charged,...Ch. 19 - Prob. 19.24PCh. 19 - Problem 19.26 Explain why the of the group of...Ch. 19 - Answer each question for A and B depicted in the...Ch. 19 - Prob. 19.27PCh. 19 - Give the IUPAC name for each compound. a....Ch. 19 - Prob. 19.29PCh. 19 - Draw the structures and give the IUPAC names for...Ch. 19 - Prob. 19.31PCh. 19 - Rank the compounds in each group in order of...Ch. 19 - 19.33 Draw the organic products formed in each...Ch. 19 - 19.34 Identify the lettered compounds in each...Ch. 19 - 19.35 Using the table in Appendix A, determine...Ch. 19 - Draw the products of each acid-base reaction, and...Ch. 19 - Which compound in each pair has the lower pKa?...Ch. 19 - 19.38 Rank the compounds in each group in order of...Ch. 19 - Rank the compounds in each group in order of...Ch. 19 - 19.40 Match the values to the appropriate...Ch. 19 - Prob. 19.41PCh. 19 - 19.42 Which carboxylic acid has the lower ,...Ch. 19 - Prob. 19.43PCh. 19 - 19.44 Explain the following statement. Although...Ch. 19 - Prob. 19.45PCh. 19 - 19.46 Explain why the of compound A is lower than...Ch. 19 - 19.47 Rank the following compounds in order of...Ch. 19 - Explain the following result. Acetic acid...Ch. 19 - 19.50 Draw all resonance structures of the...Ch. 19 - As we will see in Chapter 23, CH bonds are...Ch. 19 - Prob. 19.51PCh. 19 - The pKa of acetamide (CH3CONH2) is 16. Draw the...Ch. 19 - 19.54 Write out the steps needed to separate...Ch. 19 - Prob. 19.54PCh. 19 - Can octane and octan -1- ol be separated using an...Ch. 19 - 19.57 Identify each compound from its spectral...Ch. 19 - 19.58 Use the NMR and IR spectra given below to...Ch. 19 - 19.59 An unknown compound (molecular formula )...Ch. 19 - 19.60 Propose a structure for (molecular formula...Ch. 19 - Prob. 19.60PCh. 19 - 19.61 Match the data to the appropriate...Ch. 19 - Prob. 19.62PCh. 19 - Prob. 19.63PCh. 19 - Prob. 19.64PCh. 19 - 19.65 For each amino acid ,draw its neutral,...Ch. 19 - Calculate the isoelectric point for each amino...Ch. 19 - 19.67 Lysine and tryptophan are two amino acids...Ch. 19 - Prob. 19.68PCh. 19 - Prob. 19.69PCh. 19 - Prob. 19.70PCh. 19 - Prob. 19.71PCh. 19 - 19.71 Hydroxy butanedioic acid occurs naturally in...Ch. 19 - 19.72 Although it was initially sold as a rat...
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