Concept explainers
(a)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Figure 1
The structure of
(b)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Figure 2
The structure of
(c)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is
Therefore, the structure corresponding to the given name is,
Figure 3
The structure of
(d)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Therefore, the structure corresponding to the given name is,
Figure 4
The structure of
(e)
Interpretation: The structure corresponding to given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Figure 5
The structure of
(f)
Interpretation: The structure corresponding to given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Figure 6
The structure of
(g)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding topotassium acetate is,
Explanation of Solution
The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,
Figure 7
The structure of potassium acetate is drawn in Figure 7.
(h)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding tosodium
Explanation of Solution
The name of the compound is sodium
Figure 8
The structure of sodium
(i)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Figure 9
The structure of
(j)
Interpretation: The structure corresponding to the given name is to be stated.
Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.
Answer to Problem 19.29P
The structure corresponding to
Explanation of Solution
The name of the compound is
Figure 10
The structure of
Want to see more full solutions like this?
Chapter 19 Solutions
Organic Chemistry
- Instructions: Give the IUPAC name for each compound. A. CH₂ CH₂CH₂CH₂CCH₂COOH CH₂ B. CH.CHCHCH.COOH a CH₂CH₂ C. (CH,CH,), CHCH,CH COOH Instructions: Give the structure corresponding to each IUPAC name. a. 2-bromobutanoic acid b. 2,3-dimethylpentanoic acid c. 2-ethyl-5,5-dimethyloctanoic acid d. 3,4,5,6-tetraethyldecanoic acidarrow_forwardGive the structure corresponding to each IUPAC name. a. 2-bromobutanoic acid b. 2,3-dimethylpentanoic acid c. 3,3,4-trimethylheptanoic acid d. 2-sec-butyl-4,4-diethylnonanoic acid e. 3,4-diethylcyclohexanecarboxylic acid f. 1-isopropylcyclobutanecarboxylic acidarrow_forwardHelparrow_forward
- There are THREE parts. Please circle the final answer! Which reagent would not react with a carboxylic acid? O a. LIAIH4 b. NaOH C. KMN04 d. ВНЗ/THF An aldehyde cannot be made directly from this type of compound a. carboxylic acid O b. alcohol C. ester O d. acid chloridearrow_forwardWhat is the IUPAC name of the following compound? Br CH3 H3C O A. 5-Bromo-2-methylphenyl ethanoate B. 3-Bromo-6-methylphenyl ethanoate C. 4-Bromo-2-{oxy-(1-oxoethyl)} toluene EO D. Methyl-5-bromo-2-methyl benzoatearrow_forwardJj.149.arrow_forward
- 1. Which of the following organic compounds is the least polar? a. CH3CH2CHO b. CH3COCH3 c. CH3CH2CH2OH d. CH3CH2OCH3 e. CH3COOH 2. Which reagent can be used to convert acetic anhydride to acetic acid? a. NH3 b. CH3COO- c. CH3OH d. None of these e. H2Oarrow_forwardPredict the product.arrow_forwardMatch the letter corresponding to each structure to its proper functional group name. A. H,C CH В. H.C CH, C. HC-C-OH Ketone [ Choose ] [Choose] Alkene Carboxylic Acid Ketone Aldehydearrow_forward
- Which base is at the 5’ end of the structure shown? A.) A B.) C C.) G D.) T E.) Uarrow_forwardDraw out each compound to clearly show what groups are bonded to the carbonyl carbon. Label each compound as a carboxylic acid, ester, or amide.arrow_forwardQuestion 6 Give the reagents. O 1. BH3, 2. H₂O2, NaOH OmCPBA O 1. Hg(OAc)2, H₂O 2. NaBH4 NaBH4 OH2, Pd/C harrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY