(a) Interpretation: The structure corresponding to the given name is to be stated. Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Question

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Answer 1

Question

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10

Conclusion

The structure of 4− isopropyl −2− methyloctanedioic acid 2,2− dichloropentanedioic acid is drawn in Figure 10.

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Students have asked these similar questions

Where are the chiral centers in this molecule? Also is this compound meso yes or no?

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Where are the chiral centers in this molecule? Also is this compound meso yes or no?

Answer 2

Question

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10

Conclusion

The structure of 4− isopropyl −2− methyloctanedioic acid 2,2− dichloropentanedioic acid is drawn in Figure 10.

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Answer 3

Question

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10

Conclusion

The structure of 4− isopropyl −2− methyloctanedioic acid 2,2− dichloropentanedioic acid is drawn in Figure 10.

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Answer 4

Question

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10

Conclusion

The structure of 4− isopropyl −2− methyloctanedioic acid 2,2− dichloropentanedioic acid is drawn in Figure 10.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10

Conclusion

The structure of 4− isopropyl −2− methyloctanedioic acid 2,2− dichloropentanedioic acid is drawn in Figure 10.

Answer 6

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Answer 7

Chapter 19, Problem 19.29P

Interpretation Introduction

(a)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of the parent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 8

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 3,3− dimethylpentanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 1

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The name of the compound is 3,3− dimethylpentanoic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On third carbon atom, two methyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 2

Figure 1

Answer 13

Conclusion

The structure of 3,3− dimethylpentanoic acid is drawn in Figure 1.

Answer 14

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Answer 15

Interpretation Introduction

(b)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 16

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− chloro −3− phenylheptanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 3

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The name of the compound is 4− chloro −3− phenylheptanoic acid. The name suggests that the longest carbon chain consists of seven carbon atoms. On third and fourth carbon atoms, phenyl and chlorine groups are attached respectively. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 4

Figure 2

Answer 21

Conclusion

The structure of 4− chloro −3− phenylheptanoic acid is drawn in Figure 2.

Answer 22

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Answer 23

Interpretation Introduction

(c)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 24

Expert Solution

Answer to Problem 19.29P

The structure corresponding to (R)−2− chloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 5

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The name of the compound is (R)−2− chloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Chlorine group is attached to the second carbon atom.

The stereochemistry of the compound is determined by prioritizing the groups attached to its stereogenic center. The groups are prioritizedon the basis ofatomic number of their atoms. The configuration of the compound is R because the movement from higher priority to lower priority substituent is in anti clockwise direction and the lowest priority group is present above the plane.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 6

Figure 3

Answer 29

Conclusion

The structure of (R)−2− chloropropanoic acid is drawn in Figure 3.

Answer 30

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Answer 31

Interpretation Introduction

(d)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 32

Expert Solution

Answer to Problem 19.29P

The structure corresponding to β, β− dichloropropanoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 7

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The name of the compound is β, β− dichloropropanoic acid. The name suggests that the longest carbon chain consists of three carbon atoms. Two chlorine groups are attached to the third carbon atom.

Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 8

Figure 4

Answer 37

Conclusion

The structure of β, β− dichloropropanoic acidis drawn in Figure 4.

Answer 38

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Answer 39

Interpretation Introduction

(e)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 40

Expert Solution

Answer to Problem 19.29P

The structure corresponding to m− hydroxybenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 9

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

The name of the compound is m− hydroxybenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The hydroxyl group is attached at meta position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 10

Figure 5

Answer 45

Conclusion

The structure of m− hydroxybenzoic acid is drawn in Figure 5.

Answer 46

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Answer 47

Interpretation Introduction

(f)

Interpretation: The structure corresponding to given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 48

Expert Solution

Answer to Problem 19.29P

The structure corresponding to o− chlorobenzoic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 11

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

The name of the compound is o− chlorobenzoic acid. The name suggests that the compound contains an aromatic benzene ring. The functional group present in the compound is carboxylic acid. The chlorine group is attached at ortho position in the benzoic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 12

Figure 6

Answer 53

Conclusion

The structure of o− chlorobenzoic acidis drawn in Figure 6.

Answer 54

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Answer 55

Interpretation Introduction

(g)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 56

Expert Solution

Answer to Problem 19.29P

The structure corresponding topotassium acetate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 13

Answer 57

Expert Solution

Answer 58

Expert Solution

Answer 59

Expert Solution

Answer 60

Explanation of Solution

The name of the compound is potassium acetate. The name suggests that potassium is present in the place of hydrogen in acetic acid. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 14

Figure 7

Answer 61

Conclusion

The structure of potassium acetate is drawn in Figure 7.

Answer 62

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Answer 63

Interpretation Introduction

(h)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 64

Expert Solution

Answer to Problem 19.29P

The structure corresponding tosodium α− bromobutyrate is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 15

Answer 65

Expert Solution

Answer 66

Expert Solution

Answer 67

Expert Solution

Answer 68

Explanation of Solution

The name of the compound is sodium α− bromobutyrate. The name suggests that the longest carbon chain consists of four carbon atoms. On second carbon atom, bromine group is attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 16

Figure 8

Answer 69

Conclusion

The structure of sodium α− bromobutyrateis drawn in Figure 8.

Answer 70

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Answer 71

Interpretation Introduction

(i)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 72

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 2,2− dichloropentanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 17

Answer 73

Expert Solution

Answer 74

Expert Solution

Answer 75

Expert Solution

Answer 76

Explanation of Solution

The name of the compound is 2,2− dichloropentanedioic acid. The name suggests that the longest carbon chain consists of five carbon atoms. On second carbon atom, two chlorine groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 18

Figure 9

Answer 77

Conclusion

The structure of 2,2− dichloropentanedioic acid is drawn in Figure 9.

Answer 78

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10

Conclusion

The structure of 4− isopropyl −2− methyloctanedioic acid 2,2− dichloropentanedioic acid is drawn in Figure 10.

Answer 79

Interpretation Introduction

(j)

Interpretation: The structure corresponding to the given name is to be stated.

Concept introduction: International Union of Pure and Applied Chemistry gave guidelines to write the chemical name of molecules. There are three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of theparent name and the functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is the addition of substituents at appropriate carbon atoms.

Answer 80

Expert Solution

Answer to Problem 19.29P

The structure corresponding to 4− isopropyl −2− methyloctanedioic acid is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 19

Answer 81

Expert Solution

Answer 82

Expert Solution

Answer 83

Expert Solution

Answer 84

Explanation of Solution

The name of the compound is 4− isopropyl −2− methyloctanedioic acid. The name suggests that the longest carbon chain consists of eight carbon atoms. On second and fourth carbon atom, methyl and isopropyl groups are attached. Therefore, the structure corresponding to the given name is,

Organic Chemistry, Chapter 19, Problem 19.29P , additional homework tip 20

Figure 10