Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 19, Problem 19.24QE
(a)
Interpretation Introduction
Interpretation:
The maximum positive oxidation state of
(b)
Interpretation Introduction
Interpretation:
The maximum positive oxidation state of
(c)
Interpretation Introduction
Interpretation:
The maximum positive oxidation state of
(d)
Interpretation Introduction
Interpretation:
The maximum positive oxidation state of
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1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 19 Solutions
Chemistry Principles And Practice
Ch. 19 - Prob. 19.1QECh. 19 - Prob. 19.2QECh. 19 - Prob. 19.3QECh. 19 - Prob. 19.4QECh. 19 - Prob. 19.5QECh. 19 - Prob. 19.6QECh. 19 - Prob. 19.7QECh. 19 - Prob. 19.8QECh. 19 - Prob. 19.9QECh. 19 - Prob. 19.10QE
Ch. 19 - Prob. 19.11QECh. 19 - Prob. 19.12QECh. 19 - Prob. 19.13QECh. 19 - Prob. 19.14QECh. 19 - Prob. 19.15QECh. 19 - Prob. 19.16QECh. 19 - Prob. 19.17QECh. 19 - Prob. 19.18QECh. 19 - Prob. 19.19QECh. 19 - Prob. 19.20QECh. 19 - Prob. 19.21QECh. 19 - Prob. 19.22QECh. 19 - Prob. 19.23QECh. 19 - Prob. 19.24QECh. 19 - Prob. 19.25QECh. 19 - Prob. 19.26QECh. 19 - Prob. 19.27QECh. 19 - Prob. 19.28QECh. 19 - Prob. 19.29QECh. 19 - Prob. 19.30QECh. 19 - Prob. 19.31QECh. 19 - Prob. 19.32QECh. 19 - Prob. 19.33QECh. 19 - Prob. 19.34QECh. 19 - Prob. 19.35QECh. 19 - Prob. 19.36QECh. 19 - Prob. 19.37QECh. 19 - Prob. 19.38QECh. 19 - Prob. 19.39QECh. 19 -
What structural feature is used to determine...Ch. 19 - Prob. 19.41QECh. 19 - Prob. 19.42QECh. 19 - Prob. 19.43QECh. 19 - Prob. 19.44QECh. 19 - For each d electron configuration, state the...Ch. 19 - Prob. 19.46QECh. 19 - Prob. 19.47QECh. 19 - For the low-spin complex [Co(en)(NH3)Cl2]ClO4,...Ch. 19 - Prob. 19.49QECh. 19 - Prob. 19.50QECh. 19 - Prob. 19.51QECh. 19 - Prob. 19.52QECh. 19 - Prob. 19.53QECh. 19 - Prob. 19.54QECh. 19 - Prob. 19.55QECh. 19 - Prob. 19.56QECh. 19 - Prob. 19.57QECh. 19 - Prob. 19.58QECh. 19 - Prob. 19.59QECh. 19 - Prob. 19.60QECh. 19 - Prob. 19.61QECh. 19 - Prob. 19.62QECh. 19 - Write all the possible isomers of...Ch. 19 - Prob. 19.64QECh. 19 - Prob. 19.65QECh. 19 - Prob. 19.66QECh. 19 - Prob. 19.67QECh. 19 - Prob. 19.68QECh. 19 - Prob. 19.69QE
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