Formula of pentaaquachlorochromium(III) chloride complex has to be given. Concept Introduction: Nomenclature of coordination compounds: Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are, In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named. If one type of ligand is comes more times means it can be named with prefix: ( 1 ) mono- (usually omitted), ( 2 ) di-, ( 3 ) tri-, ( 4 ) tetra flowed by its name. Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

Question

MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

Answer 1

Question

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

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Answer 3

Question

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

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Answer 4

Question

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

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Answer 5

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 6

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

Answer 7

Chapter 19, Problem 19.31QE

(a)

Interpretation Introduction

Interpretation:

Formula of pentaaquachlorochromium(III) chloride complex has to be given.

Concept Introduction:

Nomenclature of coordination compounds:

Rules of Union of Pure and Applied Chemistry (IUPAC) system of nomenclature are,

In coordination compounds, cation name comes first then anion. Name of ligands are given in the order of alphabetical then metal cation followed by the oxidation state in Roman numeral in parentheses then the anions are named.

If one type of ligand is comes more times means it can be named with prefix: (1) mono- (usually omitted), (2) di-, (3) tri-, (4) tetra flowed by its name.

Metal in the anionic complex is named as –ate in its suffix and negative ligands are named as –ato in its suffix.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 9

(b)

Interpretation Introduction

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 10

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 11

(c)

Interpretation Introduction

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 12

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 13

(d)

Interpretation Introduction

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 14

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 15

(e)

Interpretation Introduction

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

Answer 16

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Answer 17

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Answer 19

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Answer 27

Ch. 19 - Prob. 19.1QE Ch. 19 - Prob. 19.2QE Ch. 19 - Prob. 19.3QE Ch. 19 - Prob. 19.4QE Ch. 19 - Prob. 19.5QE Ch. 19 - Prob. 19.6QE Ch. 19 - Prob. 19.7QE Ch. 19 - Prob. 19.8QE Ch. 19 - Prob. 19.9QE Ch. 19 - Prob. 19.10QE

Concept explainers

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)

Chapter 19 Solutions

Concept explainers

Interpretation: Formula of tetraamminedinitrorhodium(III) bromide complex has to be given. Concept Introduction: Refer to part (a)

Interpretation: Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given. Concept Introduction: Refer to part (a)

Interpretation: Formula of diaquatetrachlororhodate(III) complex has to be given. Concept Introduction: Refer to part (a)

Interpretation: Formula of triamminetribromoplatinum(IV) complex has to be given. Concept Introduction: Refer to part (a)

Chapter 19 Solutions

Interpretation:

Formula of tetraamminedinitrorhodium(III) bromide complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of dichlorobis(ethylenediamine)ruthenium(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of diaquatetrachlororhodate(III) complex has to be given.

Concept Introduction:

Refer to part (a)

Interpretation:

Formula of triamminetribromoplatinum(IV) complex has to be given.

Concept Introduction:

Refer to part (a)