Chemistry Principles And Practice
Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 19, Problem 19.7QE
Interpretation Introduction

Interpretation:

Only the group 1B transition elements form simple compounds in which the oxidation state of the metal is +1. For all of the other transition elements, the lowest positive oxidation state is +2 . The common feature in the electron configuration of the transition elements contributes to this fact has to be given.

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1. Give stereochemical (Fischer projection) formulas for all (but no extras) the stereoisomers that could theoretically form during the reduction of a. the carbonyl group of 2-methyl-3--pentanone b. both carbonyl groups of 2,4-pentanedione (careful!) 2. Predict the products of the reduction of O=CCH2CH2CH2C=O with a. LiAlH4 b. NaBH4 CH3 OH
Which of the following compounds can be synthesized using one reaction from any alkene, as a major product? If it can be synthesized, propose a route, and you may use any other starting materials, reagents and solvents as needed. If you do not think that it can be synthesized as a major product from an alkene, explain in detail why.
Draw the stepwise mechanism (with arrow pushing)

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