Consider the following cell reaction at 25°C. 2 Cr 3 + ( a q ) + 3 Zn ( s ) → 3 Zn 2 − ( a q ) + 2 Cr ( s ) Calculate the standard cell potential of this cell from the standard electrode potentials, and from this obtain Δ G ° for the cell reaction. Use data in Appendix C to calculate Δ H °; note that Cr(H 2 O) 6 3+ ( aq ) equals Cr 3+ ( aq ). Use these values of Δ H ° and Δ G ° to obtain Δ S ° for the cell reaction.
Consider the following cell reaction at 25°C. 2 Cr 3 + ( a q ) + 3 Zn ( s ) → 3 Zn 2 − ( a q ) + 2 Cr ( s ) Calculate the standard cell potential of this cell from the standard electrode potentials, and from this obtain Δ G ° for the cell reaction. Use data in Appendix C to calculate Δ H °; note that Cr(H 2 O) 6 3+ ( aq ) equals Cr 3+ ( aq ). Use these values of Δ H ° and Δ G ° to obtain Δ S ° for the cell reaction.
Solution Summary: The author explains that the cell potential, entropy change and free energy change of a cell should be calculated by using standard data.
2
Cr
3
+
(
a
q
)
+
3
Zn
(
s
)
→
3
Zn
2
−
(
a
q
)
+
2
Cr
(
s
)
Calculate the standard cell potential of this cell from the standard electrode potentials, and from this obtain ΔG° for the cell reaction. Use data in Appendix C to calculate ΔH°; note that Cr(H2O)63+(aq) equals Cr3+(aq). Use these values of ΔH° and ΔG° to obtain ΔS° for the cell reaction.
Part I.
a) Elucidate
the structure of compound A using the following information.
• mass spectrum: m+ = 102, m/2=57
312=29
• IR spectrum:
1002.5
% TRANSMITTANCE
Ngg
50
40
30
20
90
80
70
60
MICRONS
5
8
9 10
12
13
14 15 16
19
1740 cm
M
10
0
4000
3600
3200
2800
2400
2000
1800
1600
13
• CNMR
'H
-NMR
Peak
8
ppm (H)
Integration
multiplicity
a
1.5 (3H)
triplet
b
1.3
1.5 (3H)
triplet
C
2.3
1 (2H)
quartet
d
4.1
1 (2H)
quartet
& ppm (c)
10
15
28
60
177 (C=0)
b) Elucidate the structure of compound B using the following information
13C/DEPT NMR 150.9 MHz
IIL
1400
WAVENUMBERS (CM-1)
DEPT-90
DEPT-135
85 80 75
70
65
60
55
50
45 40
35
30 25 20
ppm
1200
1000
800
600
400
•
Part II.
a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below:
• IR spectra
% TRANSMITTANCE
1002.5
90
80
70
60
50
40
30
20
10
0
4000
3600
3200
2800
2400
2000
1800
1600
• Information from 'HAMR
MICRONS
8 9 10
11
14 15 16
19
25
1400
WAVENUMBERS (CM-1)
1200
1000
800
600
400
peak
8 ppm
Integration
multiplicity
a
2.1
1.5 (3H)
Singlet
b
3.6
1 (2H)
singlet
с
3.8
1.5 (3H)
Singlet
d
6.8
1(2H)
doublet
7.1
1(2H)
doublet
Information from 13C-nmR
Normal carbon
29ppm
Dept 135
Dept -90
+
NO peak
NO peak
50 ppm
55 ppm
+
NO peak
114 ppm
t
126 ppm
No peak
NO peak
130 ppm
t
+
159 ppm
No peak
NO peak
207 ppm
по реак
NO peak
Could you redraw these and also explain how to solve them for me pleas
Chapter 19 Solutions
OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
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Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell