OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
11th Edition
ISBN: 9781305673939
Author: Darrell Ebbing; Steven D. Gammon
Publisher: Cengage Learning US
expand_more
expand_more
format_list_bulleted
Question
Chapter 19, Problem 19.132QP
Interpretation Introduction
Interpretation:
The overall reaction should be written and cell potential (EMF) of given voltaic cell should be calculated by using standard reduction potentials.
Concept introduction:
Cell potential (EMF):
The maximum potential difference between two electrodes of voltaic cell is known as cell potential.
If standard reduction potentials of electrodes are given the cell potential (EMF) is given by,
Where,
Expert Solution & Answer

Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 19 Solutions
OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
Ch. 19.1 - Iodic acid, HIO3, can be prepared by reading...Ch. 19.1 - Balance the following equation using the...Ch. 19.2 - A voltaic cell consists of a silversilver ion...Ch. 19.2 - If you were to construct a wet cell and decided to...Ch. 19.3 - Prob. 19.4ECh. 19.3 - Prob. 19.5ECh. 19.4 - What is the maximum electrical work, that can be...Ch. 19.5 - Prob. 19.7ECh. 19.5 - Prob. 19.8ECh. 19.5 - Prob. 19.9E
Ch. 19.5 - Prob. 19.2CCCh. 19.6 - Prob. 19.10ECh. 19.6 - Prob. 19.11ECh. 19.6 - Prob. 19.12ECh. 19.7 - What is the cell potential of the following...Ch. 19.7 - What is the nickel(II)-ion concentration in the...Ch. 19.7 - Prob. 19.3CCCh. 19.8 - Prob. 19.4CCCh. 19.9 - Write the half-reactions for the electrolysis of...Ch. 19.10 - Prob. 19.16ECh. 19.11 - A constant electric current deposits 365 mg of...Ch. 19.11 - How many grams of oxygen are liberated by the...Ch. 19 - Describe the difference between a voltaic cell and...Ch. 19 - Prob. 19.2QPCh. 19 - What is the SI unit of electrical potential?Ch. 19 - Define the faraday.Ch. 19 - Why is it necessary to measure the voltage of a...Ch. 19 - Prob. 19.6QPCh. 19 - Prob. 19.7QPCh. 19 - Prob. 19.8QPCh. 19 - Prob. 19.9QPCh. 19 - Prob. 19.10QPCh. 19 - Prob. 19.11QPCh. 19 - Prob. 19.12QPCh. 19 - Prob. 19.13QPCh. 19 - Prob. 19.14QPCh. 19 - Prob. 19.15QPCh. 19 - Prob. 19.16QPCh. 19 - Briefly explain why different products are...Ch. 19 - Prob. 19.18QPCh. 19 - Prob. 19.19QPCh. 19 - What half-reaction would be expected to occur at...Ch. 19 - Prob. 19.21QPCh. 19 - The voltaic cell is represented as...Ch. 19 - Electrochemical Cells I You have the following...Ch. 19 - Electrochemical Cells II Consider this cell...Ch. 19 - Prob. 19.25QPCh. 19 - Prob. 19.26QPCh. 19 - Prob. 19.27QPCh. 19 - Prob. 19.28QPCh. 19 - Prob. 19.29QPCh. 19 - Prob. 19.30QPCh. 19 - Prob. 19.31QPCh. 19 - You have 1.0 M solutions of Al(NO3)3 and AgNO3...Ch. 19 - The zinc copper voltaic cell shown with this...Ch. 19 - The development of lightweight batteries is an...Ch. 19 - Prob. 19.35QPCh. 19 - Prob. 19.36QPCh. 19 - Balance the following oxidationreduction...Ch. 19 - Balance the following oxidationreduction...Ch. 19 - Balance the following oxidationreduction...Ch. 19 - Prob. 19.40QPCh. 19 - Balance the following oxidationreduction...Ch. 19 - Prob. 19.42QPCh. 19 - A voltaic cell is constructed from the following...Ch. 19 - Half-cells were made from a nickel rod dipping in...Ch. 19 - Zinc react spontaneously with silver ion....Ch. 19 - Prob. 19.46QPCh. 19 - A silver oxidezinc cell maintains a fairly...Ch. 19 - A mercury battery, used for hearing aids and...Ch. 19 - Write the cell notation for a voltaic cell with...Ch. 19 - Write the cell notation for a voltaic cell with...Ch. 19 - Give the notation for a voltaic cell constructed...Ch. 19 - A voltaic cell has an iron rod in 0.30 M iron(III)...Ch. 19 - Prob. 19.53QPCh. 19 - Write the overall cell reaction for the following...Ch. 19 - Consider the voltaic cell...Ch. 19 - Consider the voltaic cell...Ch. 19 - A voltaic cell whose cell reaction is...Ch. 19 - A particular voltaic cell operates on the reaction...Ch. 19 - What is the maximum work you can obtain from 30.0...Ch. 19 - Calculate the maximum work available from 50.0 g...Ch. 19 - Order the following oxidizing agents by increasing...Ch. 19 - Order the following oxidizing agents by increasing...Ch. 19 - Consider the reducing agents Cu+(aq), Zn(s), and...Ch. 19 - Prob. 19.64QPCh. 19 - Prob. 19.65QPCh. 19 - Answer the following questions by referring to...Ch. 19 - Prob. 19.67QPCh. 19 - Dichromate ion, Cr2O72, is added to an acidic...Ch. 19 - Calculate the standard cell potential of the...Ch. 19 - Calculate the standard cell potential of the...Ch. 19 - What is the standard cell potential you would...Ch. 19 - What is the standard cell potential you would...Ch. 19 - Calculate the standard free-energy change at 25C...Ch. 19 - Calculate the standard free-energy change at 25C...Ch. 19 - What is G for the following reaction?...Ch. 19 - Prob. 19.76QPCh. 19 - Calculate the standard cell potential at 25C for...Ch. 19 - Calculate the standard cell potential at 25C for...Ch. 19 - Prob. 19.79QPCh. 19 - Calculate the standard cell potential of the cell...Ch. 19 - Calculate the equilibrium constant K for the...Ch. 19 - Calculate the equilibrium constant K for the...Ch. 19 - Copper(I) ion can act as both an oxidizing agent...Ch. 19 - Prob. 19.84QPCh. 19 - Calculate the cell potential of the following cell...Ch. 19 - What is the cell potential of the following cell...Ch. 19 - Calculate the cell potential of a cell operating...Ch. 19 - Calculate the cell potential of a cell operating...Ch. 19 - The voltaic cell Cd(s)Cd2+(aq)Ni2+(1.0M)Ni(s) has...Ch. 19 - The cell potential of the following cell at 25C is...Ch. 19 - What are the half-reactions in the electrolysis of...Ch. 19 - What are the half-reactions in the electrolysis of...Ch. 19 - Describe what you expect to happen when the...Ch. 19 - Prob. 19.94QPCh. 19 - In the commercial preparation of aluminum,...Ch. 19 - Chlorine, Cl2, is produced commercially by the...Ch. 19 - When molten lithium chloride, LiCl, is...Ch. 19 - How many grams of cadmium are deposited from an...Ch. 19 - Some metals, such as iron, can be oxidized to more...Ch. 19 - Some metals, such as thallium, can be oxidized to...Ch. 19 - Balance the following skeleton equations. The...Ch. 19 - Prob. 19.102QPCh. 19 - Prob. 19.103QPCh. 19 - Prob. 19.104QPCh. 19 - Prob. 19.105QPCh. 19 - Give the notation for a voltaic cell whose overall...Ch. 19 - Prob. 19.107QPCh. 19 - Use electrode potentials to answer the following...Ch. 19 - Prob. 19.109QPCh. 19 - Prob. 19.110QPCh. 19 - a Calculate the equilibrium constant for the...Ch. 19 - Prob. 19.112QPCh. 19 - How many faradays are required for each of the...Ch. 19 - Prob. 19.114QPCh. 19 - In an analytical determination of arsenic, a...Ch. 19 - Prob. 19.116QPCh. 19 - Prob. 19.117QPCh. 19 - Prob. 19.118QPCh. 19 - A solution of copper(II) sulfate is electrolyzed...Ch. 19 - A potassium chloride solution is electrolyzed by...Ch. 19 - A constant current of 1.40 amp is passed through...Ch. 19 - A constant current of 1.25 amp is passed through...Ch. 19 - An aqueous solution of an unknown salt of gold is...Ch. 19 - An aqueous solution of an unknown salt of vanadium...Ch. 19 - An electrochemical cell is made by placing a zinc...Ch. 19 - An electrochemical cell is made by placing an iron...Ch. 19 - Prob. 19.127QPCh. 19 - a Calculate G for the following cell reaction:...Ch. 19 - Prob. 19.129QPCh. 19 - Prob. 19.130QPCh. 19 - A voltaic cell is constructed from a half-cell in...Ch. 19 - Prob. 19.132QPCh. 19 - Prob. 19.133QPCh. 19 - Order the following oxidizing agents by increasing...Ch. 19 - What is the cell potential (Ecell) of a...Ch. 19 - Prob. 19.136QPCh. 19 - Which of the following reactions occur...Ch. 19 - Prob. 19.138QPCh. 19 - The following two half-reactions arc involved in a...Ch. 19 - Prob. 19.140QPCh. 19 - Prob. 19.141QPCh. 19 - A 1.0-L sample of 1.0 M HCl solution has a 10.0 A...Ch. 19 - Consider the following cell running under standard...Ch. 19 - Prob. 19.144QPCh. 19 - Prob. 19.145QPCh. 19 - Prob. 19.146QPCh. 19 - Consider the following cell reaction at 25C....Ch. 19 - Consider the following cell reaction at 25C....Ch. 19 - Prob. 19.149QPCh. 19 - Prob. 19.150QPCh. 19 - Prob. 19.151QPCh. 19 - Prob. 19.152QPCh. 19 - An electrode is prepared by dipping a silver strip...Ch. 19 - An electrode is prepared from liquid mercury in...
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- elow are experimentally determined van Deemter plots of column efficiency, H, vs. flow rate. H is a quantitative measurement of band broadening. The left plot is for a liquid chromatography application and the night is for gas chromatography. Compare and contrast these two plots in terms of the three band broadening mechanisms presented in this activity. How are they similar? How do they differ? Justify your answers.? 0.4 H (mm) 0.2 0.1- 0.3- 0 0.5 H (mm) 8.0 7.0 6.0 5.0 4.0- 3.0 T +++ 1.0 1.5 0 2.0 4.0 Flow Rate, u (cm/s) 6.0 8.0 Flow Rate, u (cm/s)arrow_forwardPredict the products of this organic reaction: + H ZH NaBH3CN H+ n. ? Click and drag to start drawing a structure. Xarrow_forwardWhat is the missing reactant R in this organic reaction? + R H3O+ + • Draw the structure of R in the drawing area below. • Be sure to use wedge and dash bonds if it's necessary to draw one particular enantiomer. Click and drag to start drawing a structure.arrow_forward
- What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1 1. PPh3 2. n-BuLi 2 • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Click and drag to start drawing a structure.arrow_forwardThe product on the right-hand side of this reaction can be prepared from two organic reactants, under the conditions shown above and below the arrow. Draw 1 and 2 below, in any arrangement you like. 1+2 NaBH₂CN H+ N Click and drag to start drawing a structure. X $arrow_forwardExplain what is the maximum absorbance of in which caffeine absorbs?arrow_forward
- Explain reasons as to why the amount of caffeine extracted from both a singular extraction (5ml Mountain Dew) and a multiple extraction (2 x 5.0ml Mountain Dew) were severely high when compared to coca-cola?arrow_forwardProtecting Groups and Carbonyls 6) The synthesis generates allethrolone that exhibits high insect toxicity but low mammalian toxicity. They are used in pet shampoo, human lice shampoo, and industrial sprays for insects and mosquitos. Propose detailed mechanistic steps to generate the allethrolone label the different types of reagents (Grignard, acid/base protonation, acid/base deprotonation, reduction, oxidation, witting, aldol condensation, Robinson annulation, etc.) III + VI HS HS H+ CH,CH,Li III I II IV CI + P(Ph)3 V ༼ Hint: no strong base added VI S VII IX HO VIII -MgBr HgCl2,HgO HO. isomerization aqeuous solution H,SO, ༽༽༤༽༽ X MeOH Hint: enhances selectivity for reaction at the S X ☑arrow_forwardDraw the complete mechanism for the acid-catalyzed hydration of this alkene. esc 田 Explanation Check 1 888 Q A slock Add/Remove step Q F4 F5 F6 A བྲA F7 $ % 5 @ 4 2 3 & 6 87 Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Ce W E R T Y U S D LL G H IK DD 요 F8 F9 F10 F1 * ( 8 9 0 O P J K L Z X C V B N M H He commandarrow_forward
- Explanation Check F1 H₂O H₂ Pd 1) MCPBA 2) H3O+ 1) Hg(OAc)2, H₂O 2) NaBH4 OH CI OH OH OH hydration halohydrin formation addition halogenation hydrogenation inhalation hydrogenation hydration ☐ halohydrin formation addition halogenation formation chelation hydrogenation halohydrin formation substitution hydration halogenation addition Ohalohydrin formation subtraction halogenation addition hydrogenation hydration F2 80 F3 σ F4 F5 F6 1 ! 2 # 3 $ 4 % 05 Q W & Å © 2025 McGraw Hill LLC. All Rights Reserved. F7 F8 ( 6 7 8 9 LU E R T Y U A F9arrow_forwardShow the mechanism steps to obtain the lowerenergy intermediate: *see imagearrow_forwardSoap is made by the previous reaction *see image. The main difference between one soap and another soap isthe length (number of carbons) of the carboxylic acid. However, if a soap irritates your skin, they mostlikely used too much lye.Detergents have the same chemical structure as soaps except for the functional group. Detergentshave sulfate (R-SO4H) and phosphate (R-PO4H2) functional groups. Draw the above carboxylic acidcarbon chain but as the two variants of detergents. *see imagearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co

General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning

Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning

Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax

Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Introduction to Electrochemistry; Author: Tyler DeWitt;https://www.youtube.com/watch?v=teTkvUtW4SA;License: Standard YouTube License, CC-BY