(a) Interpretation: The formula of the coordination compound formed by Pt 4+ with NH 3 needs to be determined. Concept introduction: Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 1

Question

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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What is the average mass of the 10 pennies? Report your value with correct significant figures. What is the error (uncertainty) associated with each mass measurement due to the equipment? What is the uncertainty associated with the average value? Note that the uncertainty of the balance will propagate throughout the calculation. What is the standard deviation of the 10 mass measurements? Explain the difference between the propagated uncertainty and the standard deviation. Which number would you use to describe the uncertainty in the measurement? Calculate the total mass of the pennies with associated uncertainty. Calculate the average density of a penny based on these data. Propagate the uncertainty values for both mass and volume in your calculations.

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B 1 of 2 Additional problems in preparation to Midterm #1: 1.) How can the following compounds be prepared using Diels-Alder reaction: CH3 O CN (a) (b) CN CH3 2.) What is the missing reagent in the shown reaction? H3C + ? H3C H3C CN H3C ''CN (၁) H 3.) Write the products 1,2-addition and 1,4-addition of DBr to 1,3-cyclohexadiene. Remember, D is deuterium, a heavy isotope of hydrogen. It reacts exactly like hydrogen. 4.) In the shown reaction, which will be the kinetic product and which will be the thermodynamic product? H3C CI H3C HCI H3C + 5.) Which of the following molecules is aromatic? (a) (b) (c) H 6.) Which of the following molecules is aromatic? (a) (b) (c) 7.) Write the mechanism for the shown reaction. + Ха AICI 3 CI 8.) Suggest reagents that would convert benzene into the shown compounds. CI NO2 -8-6-6-8-a (a) (b) (c) (d) (e) (a) SO3H Br

Answer 2

Question

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 3

Question

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 4

Question

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

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Answer 5

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 6

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 7

Chapter 19, Problem 12QAP

Interpretation Introduction

(a)

Interpretation:

The formula of the coordination compound formed by Pt⁴⁺ with NH₃ needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The formula of the coordination compound formed by Ag⁺ with cyanide ion needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The formula of the coordination compound formed by Zn²⁺ with C₂ O₄ ²- needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The formula of the coordination compound formed by Cd²⁺ with cyanide ions needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cationic or anionic. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The total charge present on any complex ion is equal to the sum of the oxidation number of the central metal atom and the total charges of the ligand present in it.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains the formula of the coordination compound formed by Pt 4+ with NH 3 needs to be determined.

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