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Concept explainers
(a)
Interpretation:
To determine the formula and charge of nickel complex which contain four carbonyl molecules and two chloride ions.
Concept introduction:
Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The
A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus it can act as a Lewis base. It can donate its pair of electrons to the metal atom to form a coordinate bond with the transition metal atom.
(b)
Interpretation:
To determine the formula and charge of nickel complex which contain two ethylene diamine molecules.
Concept introduction:
Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands.
A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus it can act as a Lewis base. It can donate its pair of electrons to the metal atom to form a coordinate bond with the transition metal atom.
(c)
Interpretation:
To determine the formula and charge of nickel complex which contain two thiocynate molecules, two hydroxide ions and two ammonia molecules.
Concept introduction:
Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands.
A ligand is an atom or a group of atoms or an anion that has an unshared pair of electrons and thus it can act as a Lewis base. It can donate its pair of electrons to the metal atom to form a coordinate bond with the transition metal atom.

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Chapter 19 Solutions
OWLv2 with Student Solutions Manual eBook for Masterton/Hurley's Chemistry: Principles and Reactions, 8th Edition, [Instant Access], 4 terms (24 months)
- Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward(a) Sketch the 'H NMR of the following chemical including the approximate chemical shifts, the multiplicity (splitting) of all signals and the integration (b) How many signals would you expect in the 13C NMR? CH3arrow_forwardDraw the Show the major and minor product(s) for the following reaction mechanisms for both reactions and show all resonance structures for any Explain why the major product is favoured? intermediates H-Brarrow_forward
- 3. Draw ALL THE POSSBILE PRODUCTS AND THE MECHANISMS WITH ALL RESONANCE STRUCTURES. Explain using the resonance structures why the major product(s) are formed over the minor product(s). H₂SO4, HONO CHarrow_forward7. Provide the product(s), starting material(s) and/or condition(s) required for the No mechanisms required. below reaction HO + H-I CI FO Br2, FeBr3 O I-Oarrow_forward6. Design the most efficient synthesis of the following product starting from phenot Provide the reaction conditions for each step (more than one step is required) and explain the selectivity of each reaction. NO MECHANISMS ARE REQUIRED. OH step(s) CIarrow_forward
- What is the skeletal structure of the product of the following organic reaction?arrow_forwardIf a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardWhat is the major organic product of the following nucleophilic acyl substitution reaction of an acid chloride below?arrow_forward
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