(a) Interpretation: The structure of geometrical isomers (if present) of the complex [ Mn ( H 2 O ) 2 ( NO 2 ) 4 2 − ] needs to be determined. Concept introduction: Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 1

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Q1: Draw the most stable and the least stable Newman projections about the C2-C3 bond for each of the following isomers (A-C). Are the barriers to rotation identical for enantiomers A and B? How about the diastereomers (A versus C or B versus C)? enantiomers H Br H Br (S) CH3 H3C (S) (R) CH3 H3C H Br A Br H C H Br H3C (R) B (R)CH3 H Br H Br H3C (R) (S) CH3 Br H D identical

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Answer 2

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 3

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 4

Question

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

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Answer 5

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 6

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 7

Chapter 19, Problem 28QAP

Interpretation Introduction

(a)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Mn(H2O)2(NO2)42−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of geometrical isomers (if present) of the complex [Pt(NH3)3(Cl3)+] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of geometrical isomers (if present) of the complex 13 [Al(C2O4)(CO)2(Br)2−] needs to be determined.

Concept introduction:

Coordination compounds are those in which a transition metal atom is bonded to a ligand which can be neutral, cation or anion. The transition metal element is enclosed within a bracket and a charge is present on the ion to balance the charge present on the ligands. The chemical and physical properties of the complex ions and the coordination compounds formed by them depend on the spatial arrangement of ligands which are attached directly to the central metal atom.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 19 - Prob. 1QAP Ch. 19 - Prob. 2QAP Ch. 19 - Prob. 3QAP Ch. 19 - Platinum(II) forms many complexes, among them...Ch. 19 - Prob. 5QAP Ch. 19 - What is the coordination number of the central...Ch. 19 - Prob. 7QAP Ch. 19 - Prob. 8QAP Ch. 19 - Prob. 9QAP Ch. 19 - Prob. 10QAP

Solution Summary: The author explains the structure of geometrical isomers of a complex ion, which is octahedral and square planer.

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Chapter 19 Solutions