Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown. Concept introduction: In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement. To show: The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

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Answer 1

Question

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

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Answer 2

Question

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

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Check out a sample textbook solution

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Answer 3

Question

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

Expert Solution & Answer

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Answer 4

Question

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 5

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

Answer 6

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

Answer 7

Chapter 18.SE, Problem 69GP

Interpretation Introduction

Interpretation:

Given that the enzyme chorismate mutase catalyzes a Claisen rearrangement of chorismate. The structure of prephenate obtained as the product is to be shown.

Concept introduction:

In Claisen rearrangement allyl phenyl ethers undergo rearrangement when heated to 200-250°C to yield an o-allylphenol. It is a case of (3, 3) sigmatrophic rearrangement.

To show:

The structure of prephenate obtained as the product obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme chorismate mutase.

Answer 8

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Answer 9

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Answer 11

Ch. 18.1 - Name the following ethers:Ch. 18.2 - Why do you suppose only symmetrical ethers are...Ch. 18.2 - How would you prepare the following ethers using a...Ch. 18.2 - Review the mechanism of oxymercuration shown in...Ch. 18.2 - How would you prepare the following ethers? Use...Ch. 18.2 - Prob. 6P Ch. 18.3 - Prob. 7P Ch. 18.3 - Write the mechanism of the acid-induced cleavage...Ch. 18.3 - Why are HI and HBr more effective than HCl in...Ch. 18.4 - What product would you expect from Claisen...

Solution Summary: The author analyzes the structure of prephenate obtained when chorismate undergoes Claisen rearrangement catalyzed by the enzyme

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