a) Interpretation: The IUPAC name of the compound shown is to be given. Concept introduction: Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent. To give: The IUPAC name of the compound shown.

Question

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Answer 1

Question

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

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Answer 2

Question

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

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Answer 3

Question

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

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Answer 4

Question

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

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Answer 5

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

Answer 6

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Answer 7

Chapter 18.SE, Problem 39AP

Interpretation Introduction

a)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as a thioalkyl substituent.

To give:

The IUPAC name of the compound shown.

Answer 8

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Answer 9

Expert Solution

Answer 10

Expert Solution

Answer 11

Expert Solution

Answer 12

Explanation of Solution

The sulfide contains a sulfur atom attached to a cyclohexyl group and an isopropyl group.

Answer 13

Conclusion

The IUPAC name of the compound shown is cyclohexyl isopropyl sulfide.

Answer 14

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Answer 15

Interpretation Introduction

b)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Answer 16

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Answer 17

Expert Solution

Answer 18

Expert Solution

Answer 19

Expert Solution

Answer 20

Explanation of Solution

The compound contains a benzene ring with two methoxyl groups in ortho relationship.

Answer 21

Conclusion

The IUPAC name of the compound shown is 1, 2-dimethoxy benzene.

Answer 22

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Answer 23

Interpretation Introduction

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Answer 24

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Answer 25

Expert Solution

Answer 26

Expert Solution

Answer 27

Expert Solution

Answer 28

Explanation of Solution

The compound given contains a cyclopentane ring with the oxygen atom attached to C₁ and C₂.

Answer 29

Conclusion

The IUPAC name of the compound shown is 1, 2-epoxycyclopentane.

Answer 30

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Answer 31

Interpretation Introduction

d)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Answer 32

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Answer 33

Expert Solution

Answer 34

Expert Solution

Answer 35

Expert Solution

Answer 36

Explanation of Solution

The compound has a tetrahydrofuran ring with a methyl group attached on C₂.

Answer 37

Conclusion

The IUPAC name of the compound shown is 2-methyltetrahydrofuran.

Answer 38

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Answer 39

Interpretation Introduction

e)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Answer 40

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Answer 41

Expert Solution

Answer 42

Expert Solution

Answer 43

Expert Solution

Answer 44

Explanation of Solution

The compound given contains a cyclopropyl and an isopropyl group attached to an oxygen atom.

Answer 45

Conclusion

The IUPAC name of the compound shown is cyclopropyl isopropyl ether.

Answer 46

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Answer 47

Interpretation Introduction

f)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Aromatic thiols are names as derivatives of benzenethiol. The positions of the substituents, if present, are indicated by numbering from the carbon that contains SH group.

To give:

The IUPAC name of the compound shown.

Answer 48

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Answer 49

Expert Solution

Answer 50

Expert Solution

Answer 51

Expert Solution

Answer 52

Explanation of Solution

The compound given contains a benzene ring attached to a thiol group and a nitro groups in 1, 2-relationship.

Answer 53

Conclusion

The IUPAC name of the compound shown is 2-nitrobenzenethiol.

Answer 54

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Answer 55

Interpretation Introduction

g)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thial. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thial. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The IUPAC name of the compound shown.

Answer 56

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2-(isopropylthio)-3, 4-dimethylhexane.

Answer 57

Expert Solution

Answer 58

Expert Solution

Answer 59

Expert Solution

Answer 60

Explanation of Solution

In the compound shown a sulfur atom is attached to an isopropyl group and a 3, 4-dimethylhexyl group attached through C₂.

Answer 61

Conclusion

The IUPAC name of the compound shown is 2-isopropylthio-3, 4-dimethylhexane.

Answer 62

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Answer 63

Interpretation Introduction

h)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple ethers are with no other functional groups are named by identifying the two organic substituents and adding the word ether. If other functional groups are present, the ether part is considered as an alkoxy substituent.

To give:

The IUPAC name of the compound shown.

Answer 64

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Answer 65

Expert Solution

Answer 66

Expert Solution

Answer 67

Expert Solution

Answer 68

Explanation of Solution

The compound contains a three carbon straight chain with two methoxy groups attached to C₂.

Answer 69

Conclusion

The IUPAC name of the compound shown is 2, 2-dimethoxypropane.

Answer 70

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

Answer 71

Interpretation Introduction

i)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as alkylthio substituent.

To give:

The IUPAC name of the compound shown.

Answer 72

Expert Solution

Answer to Problem 39AP

The IUPAC name of the compound shown is 1, 1-(dimethylthio) cyclohexane.

Answer 73

Expert Solution

Answer 74

Expert Solution

Answer 75

Expert Solution

Answer 76

Explanation of Solution

The compound contains a cyclohexane ring with two methylthio groups attached to C₁.

Answer 77

Conclusion

The IUPAC name of the compound shown is 1, 1-dimethylthiocyclohexane.

Answer 78

Ch. 18.1 - Name the following ethers:Ch. 18.2 - Why do you suppose only symmetrical ethers are...Ch. 18.2 - How would you prepare the following ethers using a...Ch. 18.2 - Review the mechanism of oxymercuration shown in...Ch. 18.2 - How would you prepare the following ethers? Use...Ch. 18.2 - Prob. 6P Ch. 18.3 - Prob. 7P Ch. 18.3 - Write the mechanism of the acid-induced cleavage...Ch. 18.3 - Why are HI and HBr more effective than HCl in...Ch. 18.4 - What product would you expect from Claisen...

Concept explainers

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Want to see more full solutions like this?

Chapter 18 Solutions

Concept explainers

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

c) Interpretation: The IUPAC name of the compound shown is to be given. Concept introduction: The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached. To give: The IUPAC name of the compound shown.

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Answer to Problem 39AP

Explanation of Solution

Want to see more full solutions like this?

Chapter 18 Solutions

c)

Interpretation:

The IUPAC name of the compound shown is to be given.

Concept introduction:

The epoxides are named by identifying the ring and the positions on the ring to which the oxygen atom is attached.

To give:

The IUPAC name of the compound shown.