Organic Chemistry
Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 18.8, Problem 16P
Interpretation Introduction

a)

Organic Chemistry, Chapter 18.8, Problem 16P , additional homework tip  1

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –thiol. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

b)

Organic Chemistry, Chapter 18.8, Problem 16P , additional homework tip  2

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Thioalcohols are named as derivatives of the parent alkane using the suffix –al. The longest carbon chain containing the thiol group is chosen and the parent name is derived by replacing the ending –e with –thiol. The alkane chain is numbered beginning at the end nearer to the thiol group. The substituents are numbered according to their position on the chain. The name is written listing the substituents in the alphabetical order and indicating the position to which –SH is bonded.

To give:

The name of the compound shown.

Interpretation Introduction

c)

Organic Chemistry, Chapter 18.8, Problem 16P , additional homework tip  3

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

In naming cyclic thioalcohols the parent name is derived from the cycloalkene ring by replacing –e of the cycloalkene with –thiol. The ring is numbered from the carbon with –SH in such a way that lowest number possible is given to the other functional groups present.

To give:

The name of the compound shown.

Interpretation Introduction

d)

Organic Chemistry, Chapter 18.8, Problem 16P , additional homework tip  4

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the sulfide shown.

Interpretation Introduction

e)

Organic Chemistry, Chapter 18.8, Problem 16P , additional homework tip  5

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the disulfide shown.

Interpretation Introduction

f)

Organic Chemistry, Chapter 18.8, Problem 16P , additional homework tip  6

Interpretation:

The name of the compound given is to be stated.

Concept introduction:

Simple sulfides are with no other functional groups are named by identifying the two organic substituents and adding the word sulfide. If other functional groups are present, the sulfide part is considered as an alkylthio substituent.

To give:

The name of the compound shown.

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Chapter 18 Solutions

Organic Chemistry

Ch. 18.5 - Prob. 11PCh. 18.6 - Predict the major product of each of the following...Ch. 18.6 - Prob. 13PCh. 18.6 - Predict the major product of the following...Ch. 18.7 - 15-Crown-5 and 12-crown-4 ethers complex Na+ and...Ch. 18.8 - Prob. 16PCh. 18.8 - 2-Butene-l-thiol is one component of skunk spray....Ch. 18.9 - The 1H NMR spectrum shown is that of a cyclic...Ch. 18.SE - Give IUPAC names for the following compounds...Ch. 18.SE - Show the product, including stereochemistry, that...Ch. 18.SE - Prob. 21VCCh. 18.SE - Treatment of the following alkene with a...Ch. 18.SE - Prob. 23MPCh. 18.SE - Prob. 24MPCh. 18.SE - Predict the product(s) and provide the mechanism...Ch. 18.SE - The alkoxymercuration of alkenes involves the...Ch. 18.SE - Predict the product(s) and provide the mechanism...Ch. 18.SE - Predict the product(s) and provide the mechanism...Ch. 18.SE - Prob. 29MPCh. 18.SE - Ethers undergo an acid-catalyzed cleavage reaction...Ch. 18.SE - Treatment of 1, 1-diphenyl-l, 2-epoxyethane with...Ch. 18.SE - Fluoxetine, a heavily prescribed antidepressant...Ch. 18.SE - When 2-methyl-2, 5-pentanediol is treated with...Ch. 18.SE - Prob. 34MPCh. 18.SE - Prob. 35MPCh. 18.SE - Aldehydes and ketones undergo acid-catalyzed...Ch. 18.SE - Propose a mechanism to account for the following...Ch. 18.SE - Prob. 38APCh. 18.SE - Prob. 39APCh. 18.SE - How would you prepare the following ethers?Ch. 18.SE - Prob. 41APCh. 18.SE - tert-Butyl ethers can be prepared by the reaction...Ch. 18.SE - Treatment of trans-2-chlorocyclohexanol with NaOH...Ch. 18.SE - Predict the products of the following ether...Ch. 18.SE - Prob. 45APCh. 18.SE - Prob. 46APCh. 18.SE - Write the mechanism of the hydrolysis of cis-5,...Ch. 18.SE - Prob. 48APCh. 18.SE - Acid-catalyzed hydrolysis of a 1,...Ch. 18.SE - Prob. 50APCh. 18.SE - Epoxides are reduced by treatment with lithium...Ch. 18.SE - Prob. 52APCh. 18.SE - The red fox (Vulpes vulpes) uses a chemical...Ch. 18.SE - Anethole, C10H12O, a major constituent of the oil...Ch. 18.SE - Propose structures for compounds that have the...Ch. 18.SE - Prob. 56GPCh. 18.SE - How would you synthesize anethole (Problem 18-54)...Ch. 18.SE - How could you prepare benzyl phenyl ether from...Ch. 18.SE - Meerwein's reagent, triethyloxonium...Ch. 18.SE - Prob. 60GPCh. 18.SE - Prob. 61GPCh. 18.SE - The Zeisel method is an old analytical procedure...Ch. 18.SE - Prob. 63GPCh. 18.SE - Prob. 64GPCh. 18.SE - Prob. 65GPCh. 18.SE - Identify the reagents a-e in the following scheme:Ch. 18.SE - Propose structures for compounds that have the...Ch. 18.SE - Prob. 68GPCh. 18.SE - Prob. 69GPCh. 18.SE - Predict the product(s) if the starting materials...
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