
(a)
Interpretation:
The change in entropy in the given vaporization process has to be explained.
Concept Introduction:
Entropy is a
Entropy is the measure of randomness in the system. Standard entropy change in a reaction is the difference in entropy of the products and reactants.
Where,
Standard entropy change in a reaction and entropy change in the system are same.
(b)
Interpretation:
The change in entropy in the given melting process has to be explained.
Concept Introduction:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
Entropy is the measure of randomness in the system. Standard entropy change in a reaction is the difference in entropy of the products and reactants.
Where,
Standard entropy change in a reaction and entropy change in the system are same.
(c)
Interpretation:
The change in entropy for the given sublimating process has to be explained.
Concept Information:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
Entropy is the measure of randomness in the system. Standard entropy change in a reaction is the difference in entropy of the products and reactants.
Where,
Standard entropy change in a reaction and entropy change in the system are same.
(d)
Interpretation:
The change in entropy in the given sublimating process has to be explained.
Concept Introduction:
Entropy is a thermodynamic quantity, which is the measure of randomness in a system. The term entropy is useful in explaining the spontaneity of a process. For all spontaneous process in an isolated system there will be an increase in entropy. Let us consider the example of diffusion of gas molecule to understand the concept of entropy. When a perfume bottle is opened the fragrance is immediately spread into the surroundings. Inside the bottle the gas molecules are close to each other and entropy is less. Once the bottle is opened the gas molecules escapes into the surroundings and have more disorderly arrangements.
Entropy is the measure of randomness in the system. Standard entropy change in a reaction is the difference in entropy of the products and reactants.
Where,
Standard entropy change in a reaction and entropy change in the system are same.

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Chapter 18 Solutions
General Chemistry
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- Ideally nonpolarizable electrodes can1. participate as reducers in reactions.2. be formed only with hydrogen.3. participate as oxidizers in reactions.4. form open and closed electrochemical systems.arrow_forwardIndicate the options for an electrified interface:1. Temperature has no influence on it.2. Not all theories that describe it include a well-defined electrical double layer.3. Under favorable conditions, its differential capacitance can be determined with the help of experimental measurements.4. A component with high electronic conductivity is involved in its formation.arrow_forwardTo describe the structure of the interface, there are theories or models that can be distinguished by:1. calculation of the charge density.2. distribution of ions in the solution.3. experimentally measured potential difference.4. external Helmoltz plane.arrow_forward
- Indicate the correct options when referring to Luther's equation:1. It is not always easy to compare its results with experimental results.2. It depends on the number of electrons exchanged in the species involved.3. Its foundation is thermodynamic.4. The values calculated with it do not depend on temperature.arrow_forwardIndicate which of the unit options correspond to a measurement of current density.1. A s m-22. mC s-1 m-23. Ω m-24. V J-1 m-2arrow_forwardIndicate the options that are true when referring to electrode membranes:1. The Donnan potential, in general, does not always intervene in membranes.2. There are several ways to classify the same membrane.3. Any membrane can be used to determine the pH of a solution.4. Only one solution and one membrane are needed to determine the pH of that solution.arrow_forward
- Calculate the maximum volume of carbon dioxide gasarrow_forwardIn galvanic cells, their potential1. can be measured with a potentiometer2. does not depend on the equilibrium constant of the reaction occurring within them3. is only calculated from the normal potentials of the electrodes they comprise4. can sometimes be considered a variation in a potential differencearrow_forwardIf some molecules in an excited state collide with other molecules in a ground state, this process1. can occur in solution and in the gas phase.2. can be treated as a bimolecular process.3. always results in collisional deactivation.4. does not compete with any other process.arrow_forward
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