ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 18.3, Problem 2CC
Interpretation Introduction

Interpretation:

The mechanism for the following reaction has to be outlined –

                       ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL), Chapter 18.3, Problem 2CC , additional homework tip  1

Concept Introduction:

Electrophilic substitution reaction is a type of reaction in which a particular group or atom in a compound is replaced by electrophile. An electrophile is an species that is deficient of electrons.

Sulfonation of benzene is a type of electrophilic substitution reaction in which one of the six Hydrogen atoms in benzene is substituted by -SO3H group. The given reaction,

          ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL), Chapter 18.3, Problem 2CC , additional homework tip  2

is reverse reaction of the Sulfonation of benzene. So to predict the mechanism for the above reaction the mechanism of the Sulfonation reaction of benzene has to be understood clearly.

The reaction of sulfonation of benzene can be represented as  -

              ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL), Chapter 18.3, Problem 2CC , additional homework tip  3

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A first order reaction is 46.0% complete at the end of 59.0 minutes. What is the value of k? What is the half-life for this reaction? HOW DO WE GET THERE? The integrated rate law will be used to determine the value of k. In [A] [A]。 = = -kt What is the value of [A] [A]。 when the reaction is 46.0% complete?
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