ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 18.13, Problem 31CC
Interpretation Introduction

Interpretation:

The synthesis of the following compound has to be illustrated using benzene as the starting compound.

                                                  ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL), Chapter 18.13, Problem 31CC

Concept Introduction:

  • Electrophilic substitution reactions of aromatic compounds are known as aromatic electrophilic substitution reactions. An electrophile is a species that is deficient of electrons.
  • Benzene is an electron rich Aromatic compound. It undergoes aromatic electrophilic substitution reaction.  The delocalized nature of pi electrons in benzene attributes a special property to benzene called resonance.
  • The various types of electrophilic substitution reactions in benzene are – Chlorination, Bromination, Nitration, Sulfonation, Friedel Crafts Alkylation/Acylation etc.
  • Apart from electrophilic substitution reactions benzene and its derivatives also undergo another special type of reactions namely Aromatic nucleophilic substitution reactions.
  • The criteria for aromatic nucleophilic substitution reaction to occur are –
  • The aromatic ring must contain a strong electron withdrawing group
  • The aromatic ring must contain a leaving group
  • The leaving group must be posited either ortho or para position to the strong electron withdrawing group.

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Organic Chemistry Esterification reactions 1. Write the steps to prepare ester. 2. Write complete reaction of ethanol and acetic acid to make ester. 3. What does ester smell like? What are the uses of ester. 4. What the role of sulfuric acid in the esterification reaction
11. Complete the following esterification reaction with names of all the reactants and products under. Hint: Remove the water and end up with ester R-C-OH + ROH R-C-OR + H₂O A carboxylic acid An alcohol An ester Water BYJU'S H-C-C O-H Нин C-C-C-H HAAA H O-C-C-C-H AAA Ethanoic acid Propanol Water Propyl ethanoate By com CH3COOH + CH3CH2CH2CH₂CH₂OH → Practice for alcohols aldehydes and ketones: 12. Draw the structures from the following names mixed of alcohol/aldehyde and ketone: a. 4-methyl cyclohexanone b. 3-methyl-2-pentenal c. 2,3-dimethylcyclohexanone d. 1,3propanediol or Propane 1,3 diol 13. Write systematic names for the following compounds identify functional group: a. b. (CH3)2CH-C OH c) CH(CH₂)-- OH -,-,
may you please show all steps! i am having a hard time understanding and applying in this format, thank you!

Chapter 18 Solutions

ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)

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