(a) Interpretation: The structure corresponding to 3-hexanamine is to be drawn. Concept Introduction: Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as- Primary amines ( RNH 2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group. Secondary amines ( R 2 NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups. Tertiary amine ( R 3 N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 1

Question

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.). A) Predict whether decreasing the column inner diameters increase or decrease bandwidth. B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or decreasing bandwidth as a function of i.d. and justify your answer. Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles. 35 20 H(um) 큰 20 15 90 0+ 1500 100 75 550 01 02 594 05 μ(cm/sec) 30 15 10

Answer 2

Question

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 3

Question

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 4

Question

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 5

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 6

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 7

Chapter 18.2, Problem 18.5P

Interpretation Introduction

(a)

Interpretation:

The structure corresponding to 3-hexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines (RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure corresponding to N-methylpentylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

) Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure corresponding to p-nitroaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure corresponding to N-methylpiperidine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure corresponding to N,N-dimethylethylamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The structure corresponding to 2-aminocyclohexanone is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The structure corresponding to 1-propylcyclohexanamine is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 20

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 21

Interpretation Introduction

(h)

Interpretation:

The structure corresponding to N-propylaniline is to be drawn.

Concept Introduction:

Amines are organic compound which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as-

Primary amines ( RNH2) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 22

Expert Solution & Answer

Answer 23

Expert Solution & Answer

Answer 24

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Answer 25

Ch. 18.1 - Prob. 18.1PP Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.2 - Prob. 18.2PP Ch. 18.2 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.3 - Prob. 18.3PP Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P

Solution Summary: The author explains the structure corresponding to 3-hexanamine. Amines are organic compound derived from ammonia by replacing one or more hydrogen atoms by the alkyl groups.

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