(a) Interpretation: The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)- Concept Introduction: Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as Primary amines ( RNH 2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group. Secondary amines ( R 2 NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups. Tertiary amine ( R 3 N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

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Answer 1

Question

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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Answer 2

Question

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

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Answer 3

Question

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

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Answer 4

Question

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

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Answer 5

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

Answer 6

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 7

Chapter 18.1, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The amine in the methamphetamine is to be labeled as 1°(primary), 2° (secondary) or 3°(tertiary)-

Concept Introduction:

Amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms of ammonia by the alkyl groups. The amines can be classified as

Primary amines ( RNH2 ) - When one hydrogen of ammonia is replaced by the alkyl or aryl group.

Secondary amines ( R2NH ) - When two hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Tertiary amine ( R3N ) - When all three hydrogen atoms of ammonia are replaced by the alkyl or aryl groups.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

Answer 9

Interpretation Introduction

(b)

Interpretation:

The molecular shape around each indicated atom in the methamphetamine is to be given.

Concept Introduction:

Molecular shape is defined as the 3-D arrangement of atoms in a molecule.

The molecular shape of sp² hybridized atom is trigonal planar.

According to VSEPR-

Number of atoms bonded to the central atom Number of lone pairs Molecular shape
2 0 Linear
2 1 Bent
3 0 Trigonal planar
3 1 Trigonal pyramidal
4 0 Tetrahedral

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18.1 - Prob. 18.1PP Ch. 18.1 - Prob. 18.1P Ch. 18.1 - Prob. 18.2P Ch. 18.1 - Prob. 18.3P Ch. 18.2 - Prob. 18.2PP Ch. 18.2 - Prob. 18.4P Ch. 18.2 - Prob. 18.5P Ch. 18.3 - Prob. 18.3PP Ch. 18.4 - Decaffeinated coffee is produced by extracting the...Ch. 18.4 - Prob. 18.7P

Solution Summary: The author explains that amines are organic compounds which are derived from ammonia by replacing one or more hydrogen atoms by the alkyl groups.

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Chapter 18 Solutions

Number of atoms bonded to the central atom	Number of lone pairs	Molecular shape
2	0	Linear
2	1	Bent
3	0	Trigonal planar
3	1	Trigonal pyramidal
4	0	Tetrahedral