The conversion of hexanoic acid to given amine has to be shown. Concept introduction: Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride. Reaction of acid chloride with ammonia or amines : The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide. The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound. L i A l H 4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

Question

Predict the product formed when the compound shown below undergoes a reaction with MCPBA in CH2Cl2. MCPBA is meta-chloroperoxybenzoic acid.

Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

Interpretation:

The conversion of hexanoic acid to given amine has to be shown.

Concept introduction:

Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride.

Reaction of acid chloride with ammonia or amines:

The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.

The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.

LiAlH4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

(b)

Interpretation Introduction

Interpretation:

The conversion of hexanoic acid to given amine has to be shown.

Concept introduction:

Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride.

Reaction of acid chloride with ammonia or amines:

The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.

The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.

LiAlH4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

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Predict the product formed when the compound shown below undergoes a reaction with MCPBA in CH2Cl2. MCPBA is meta-chloroperoxybenzoic acid.

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Answer 2

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

Interpretation:

The conversion of hexanoic acid to given amine has to be shown.

Concept introduction:

Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride.

Reaction of acid chloride with ammonia or amines:

The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.

The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.

LiAlH4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

(b)

Interpretation Introduction

Interpretation:

The conversion of hexanoic acid to given amine has to be shown.

Concept introduction:

Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride.

Reaction of acid chloride with ammonia or amines:

The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.

The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.

LiAlH4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

Expert Solution & Answer

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Check out sample textbook solution

Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction

Interpretation:

The conversion of hexanoic acid to given amine has to be shown.

Concept introduction:

Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride.

Reaction of acid chloride with ammonia or amines:

The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.

The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.

LiAlH4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

(b)

Interpretation Introduction

Interpretation:

The conversion of hexanoic acid to given amine has to be shown.

Concept introduction:

Acid chlorides are most often prepared by treating a carboxylic acid with thionyl chloride.

Reaction of acid chloride with ammonia or amines:

The reaction of acid chlorides with ammonia and primary and secondary amines will yield amide.

The nucleophilic addition of ammonia or amine to the carbonyl carbon occurs which is followed by a proton transfer forming an addition intermediate that will eliminate chloride and lose a proton to give the amide compound.

LiAlH4 is a powerful reducing agent which reduces carboxylic acids to primary alcohol.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 18.10, Problem 18.10P

(a)

Interpretation Introduction