(a)
Interpretation:
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of esters of carboxylic acids:
The acyl group bonded to
The naming of an ester of a
(a)
Explanation of Solution
The name of the compound is given below:
Dimethyl carbonate
From the name, it is clear that two methyl groups are attached to oxygen atoms in the compound and the parent ester group is carbonate.
Thus, the structure of the compound is given below:
(b)
Interpretation:
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of nitriles:
The numbering 1 can be given to the nitrile carbon atom and add nitrile to end of the
(b)
Explanation of Solution
The name of the compound is given below:
The functional group is nitrile and benzene ring is attached to it.
Thus, the structure of the compound is given below:
Benzo nitrile
(c)
Interpretation:
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of esters of carboxylic acids:
The acyl group bonded to
The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.
(c)
Explanation of Solution
The name of the compound is given below:
Isopropyl-3-methylhexanoate
The alkyl group attached on oxygen atom is the isopropyl group and the parent chain is the methylhexanoate.
Thus, the structure of the compound is given below:
(d)
Interpretation:
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of esters of carboxylic acids:
The acyl group bonded to
The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.
(d)
Explanation of Solution
The name of the compound is given below:
Diethyl oxalate
From the name, it is clear that two ethyl groups are attached to oxygen atoms in the compound and the parent ester group is oxalate.
Thus, the structure of the compound is given below:
(e)
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of esters of carboxylic acids:
The acyl group bonded to
The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.
(e)
Explanation of Solution
The name of the compound is given below:
Ethyl (Z)-2-pentenoate
The alkyl group attached on oxygen atom is the ethyl group and the parent chain is the pentenoate. The double bond is having E configuration.
Thus, the structure of the compound is given below:
(f)
Interpretation:
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of anhydrides:
The nomenclature of anhydride involves replacement of the word acid with anhydride. In the case of mixed anhydrides, both acids should be named.
(f)
Explanation of Solution
The name of the compound is given below:
Butanoic anhydride
From the butanoic acid, acid part can be replaced with an anhydride group.
(g)
Interpretation:
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of amides and imides:
The acyl group bonded to a nitrogen atom is the functional group of an amide.
The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.
The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘
The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom
(g)
Explanation of Solution
The name of the compound is given below:
Dodecanamide:
The functional group is amide and the acyl group attached is the dodecane group.
Thus, the structure of the compound is given below:
(h)
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of esters of carboxylic acids:
The acyl group bonded to
The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.
(h)
Explanation of Solution
The name of the compound is given below:
Ethyl-3-hydroxybutanoate
The alkyl group attached on oxygen atom is the ethyl group and the parent chain is the butanoate and a hydroxyl group is present in the third position.
Thus, the structure of the compound is given below:
(i)
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of acid chlorides:
The nomenclture of acid chlorides can be done by replacing –oic acid with –oyl chloride.
(i)
Explanation of Solution
The name of the compound is given below:
Octanoyl chloride
The acid group from the octanoic acid will be replaced by acid chloride group.
Thus, the structure of the compound is given below:
(j)
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of esters of carboxylic acids:
The acyl group bonded to
The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.
(j)
Explanation of Solution
The name of the compound is given below:
Diethyl cis-1,2-cyclohexanedicarboxylate
The alkyl group attached on oxygen atom are two ethyl groups and the parent chain is the dicarboxylate and a cyclohecxane group is present in the 1,2 position.
Thus, the structure of the compound is given below:
(k)
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of acid chlorides:
The nomenclture of acid chlorides can be done by replacing –oic acid with –oyl chloride.
(k)
Explanation of Solution
The name of the compound is given below:
Methanesulfonyl chloride
The acid group from the methanesulfonic acid will be replaced by acid chloride group.
Thus, the structure of the compound is given below:
(l)
The structural formula for the given compound has to be drawn.
Concept introduction:
Nomenclature of acid chlorides:
The nomenclture of acid chlorides can be done by replacing –oic acid with –oyl chloride.
(l)
Explanation of Solution
The name of the compound is given below:
p-Toluenesulfonyl chloride
The acid group from the p-toluenesulfonic acid will be replaced by acid chloride group.
Thus, the structure of the compound is given below:
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Chapter 18 Solutions
ORGANIC CHEMISTRY-OWL V2 ACCESS
- Don't used Ai solutionarrow_forwardDon't used Ai solutionarrow_forward5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15% glycerin by weight. If the original charge is 500 kg, evaluate; e. The ratio of sucrose to water in the original charge (wt/wt). f. Moles of CO2 evolved. g. Maximum possible amount of ethanol that could be formed. h. Conversion efficiency. i. Per cent excess of excess reactant. Reactions: Inversion reaction: C12H22O11 + H2O →2C6H12O6 Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2 Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3arrow_forward
- Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?arrow_forward13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. cleavage Bond A •CH3 + 26.← Cleavage 2°C. + Bond C +3°C• CH3 2C Cleavage E 2°C. 26. weakest bond Intact molecule Strongest 3°C 20. Gund Largest argest a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. C Weakest bond A Produces Most Bond Strongest Bond Strongest Gund produces least stable radicals Weakest Stable radical b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 13°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. • CH3 methyl radical Formed in Gund A Cleavage c.…arrow_forwardBr. COOH Br, FCH COOH E FeBr ASOCI B NH (CH,CO),OD Br₂ 2 C alcKOHarrow_forward
- Find A to F (all)arrow_forwardShow work. don't give Ai generated solutionarrow_forwardHi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward
- Hi!! Please provide a solution that is handwritten. Ensure all figures, reaction mechanisms (with arrows and lone pairs please!!), and structures are clearly drawn to illustrate the synthesis of the product as per the standards of a third year organic chemistry course. ****the solution must include all steps, mechanisms, and intermediate structures as required. Please hand-draw the mechanisms and structures to support your explanation. Don’t give me AI-generated diagrams or text-based explanations, no wordy explanations on how to draw the structures I need help with the exact mechanism hand drawn by you!!! I am reposting this—ensure all parts of the question are straightforward and clear or please let another expert handle it thanks!!arrow_forward. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the molecule depicted below. Bond B 2°C. +2°C. < cleavage Bond A • CH3 + 26. t cleavage 2°C• +3°C• Bond C Cleavage CH3 ZC '2°C. 26. E Strongest 3°C. 2C. Gund Largest BDE weakest bond In that molecule a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in appropriate boxes. Weakest C bond Produces A Weakest Bond Most Strongest Bond Stable radical Strongest Gund produces least stable radicals b. (4pts) Consider the relative stability of all cleavage products that form when bonds A, B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B, and C are all carbon radicals. i. Which ONE cleavage product is the most stable? A condensed or bond line representation is fine. 人 8°C. formed in bound C cleavage ii. Which ONE cleavage product is the least stable? A condensed or bond line representation is fine. methyl radical •CH3 formed in bund A Cleavagearrow_forwardWhich carbocation is more stable?arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage Learning