Concept explainers
(a)
Interpretation:
The structure of 1-decanamine needs to be determined.
Concept Introduction:
The name of the
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(b)
Interpretation:
The structure of tricyclohexylamine needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(c)
Interpretation:
The structure of p-bromoaniline needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(d)
Interpretation:
The structure of 3-aminobutanoic needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(e)
Interpretation:
The structure of N, N-dipropyl-2-octanmine needs to be determined.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.
(f)
Interpretation:
The structure of N-ethylhexylamine needs to be drawn.
Concept Introduction:
The name of the amines is written based on their structure that whether they are primary, secondary or tertiary. The name of the primary amine is written using the longest carbon chain having the amine group. At the end of the name of the parent alkane chain, the suffix amine is added.
In the case of secondary and tertiary amines, if there are more than 1 same alkyl groups present, they are named using prefix di- or tri- along with the primary amine name. If there is more than one type of alkyl groups, they are named as N-substituted primary amines.

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Chapter 18 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
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