General Chemistry: Principles and Modern Applications (11th Edition)
11th Edition
ISBN: 9780132931281
Author: Ralph H. Petrucci, F. Geoffrey Herring, Jeffry D. Madura, Carey Bissonnette
Publisher: PEARSON
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Chapter 18, Problem 23E
Can the solubility of
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A chemistry graduate student is given 450. mL of a 1.00M chlorous acid (HClO₂) solution. Chlorous acid is a weak acid
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with K = 1.1 × 10 . What mass of NaClO₂ should the student dissolve in the HClO2 solution to turn it into a buffer with
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You may assume that the volume of the solution doesn't change when the NaClO₂ is dissolved in it. Be sure your answer
has a unit symbol, and round it to 2 significant digits.
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A chemistry graduate student is given 500. mL of a 1.50M chlorous acid (HClO₂) solution. Chlorous acid is a weak acid with K=1.1 × 10
KClO₂ should the student dissolve in the HClO₂ solution to turn it into a buffer with pH = 1.87?
You may assume that the volume of the solution doesn't change when the KClO₂ is dissolved in it. Be sure your answer has a unit symbol, and round it to 2
significant digits.
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A chemistry graduate student is given 450. mL of a 1.70M hydrocyanic acid (HCN) solution. Hydrocyanic acid is a weak acid with K,= 4.9 × 10 ".
What
mass of KCN should the student dissolve in the HCN solution to turn it into a buffer with pH = 8.97?
You may assume that the volume of the solution doesn't change when the KCN is dissolved in it. Be sure your answer has a unit symbol, and round it to 2
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Chapter 18 Solutions
General Chemistry: Principles and Modern Applications (11th Edition)
Ch. 18 - Write K10 expressions for the following...Ch. 18 - Write solubility equilibrium equations that are...Ch. 18 - The following K10 values ate found in a handbook....Ch. 18 - Calculate the aqueous solubility, in moles per...Ch. 18 - Prob. 5ECh. 18 - Which of the following saturated aqueous solutions...Ch. 18 - Fluoridated drinking water contains about 1 part...Ch. 18 - In the qualitative cation analysis procedure, Bi2+...Ch. 18 - Prob. 9ECh. 18 - A 725mL sample of a saturated solution of calcium...
Ch. 18 - A 25.00mL sample of a clear saturated solution of...Ch. 18 - A 250 mL sample of saturated CaC2O4 (aq) requires...Ch. 18 - Prob. 13ECh. 18 - Prob. 14ECh. 18 - Calculate the molar solubility of...Ch. 18 - How would you expect the presence of the following...Ch. 18 - Prob. 17ECh. 18 - Describe the effect of the salt NNO2 on the...Ch. 18 - A 0.150 M Na2SO4 , solution that is saturated with...Ch. 18 - It 100.0 mL of 0. 0025 U Na2SO4(aq) is saturated...Ch. 18 - What [Pb2+] should be maintained in Pb( NO2)2(aq)...Ch. 18 - What [l-] should be maintained in Kl(aq) to...Ch. 18 - Can the solubility of Ag2CrO4 be lowered to 5.0104...Ch. 18 - Prob. 24ECh. 18 - Prob. 25ECh. 18 - Prob. 26ECh. 18 - Will prectiation of MgF2(s) occur if a 22.5 mg...Ch. 18 - Will pbCl2 precitate when 155mL of 0.016M KCl(aq)...Ch. 18 - What is the minimum pH at which Cd(OH)2(s) will...Ch. 18 - What is the minimum pH at which Cr(OH)2(s) will...Ch. 18 - Will precipitation occur in the following cases?...Ch. 18 - Prob. 32ECh. 18 - Prob. 33ECh. 18 - Prob. 34ECh. 18 - When 200.0 ml. of 0 350 N K2CrO4(aq) are added to...Ch. 18 - What percentage of the original Ag4 remains in...Ch. 18 - Prob. 37ECh. 18 - The ancient Romans added calcium sulfate to wine...Ch. 18 - Prob. 39ECh. 18 - Prob. 40ECh. 18 - Kl(aq) is slowly added to a solution with...Ch. 18 - A solution is 0010 M en both CrO42- and SO42 . To...Ch. 18 - An aqueous solution that 200 U m AgNO2 slowly...Ch. 18 - AgNO2(aq) is slowly added to a solution that is...Ch. 18 - Which of the following solids is (are) more...Ch. 18 - Which of the blowing solids is (are) more soluble...Ch. 18 - The solubility of Mg(OH)2 m a particualr buffer...Ch. 18 - To 0.350L of 0.150MNH2 is added 0.150 L of 0.100 M...Ch. 18 - For the equilibrium...Ch. 18 - Will the following precipitates form under the...Ch. 18 - Prob. 51ECh. 18 - Prob. 52ECh. 18 - In a solution that is 0.0500M in [Cu( CN)4]2 and...Ch. 18 - Calculate [Cu2+] in a 0.10M CuSO4(aq) solution...Ch. 18 - Prob. 55ECh. 18 - A solution is 0.10 M in free NH2 ,0.10M in NH4Cl ,...Ch. 18 - A 0.10 mol sample of AgNO2(s) is dissolved in...Ch. 18 - A solution is prepared at has [NH2]=1.00M and...Ch. 18 - Prob. 59ECh. 18 - A solution is 0.05 U m Cu2+ in Hg2+ , and in Mn2+...Ch. 18 - Prob. 61ECh. 18 - Prob. 62ECh. 18 - Suppose you did a group 1 qualitative cation...Ch. 18 - Prob. 64ECh. 18 - Prob. 65ECh. 18 - Prob. 66ECh. 18 - Prob. 67IAECh. 18 - A handbook lists the solubility of CaHPO4 as 0.32g...Ch. 18 - Prob. 69IAECh. 18 - What percentage of the Ba2+ in solution is...Ch. 18 - Prob. 71IAECh. 18 - Prob. 72IAECh. 18 - Prob. 73IAECh. 18 - What is the solubility of MnS, in grams per liter,...Ch. 18 - Prob. 75IAECh. 18 - Prob. 76IAECh. 18 - Prob. 77IAECh. 18 - Prob. 78IAECh. 18 - Prob. 79IAECh. 18 - Prob. 80IAECh. 18 - Prob. 81IAECh. 18 - Prob. 82IAECh. 18 - Prob. 83IAECh. 18 - Prob. 84IAECh. 18 - A 2509 sample of Ag2SO4(s) added to a beaker...Ch. 18 - Prob. 86IAECh. 18 - Prob. 87FPCh. 18 - In the Mohr titration, Cl(aq) is titrated with...Ch. 18 - The accompanying drawing suggests a series of...Ch. 18 - Prob. 90SAECh. 18 - Briefly describe each of the following ideas,...Ch. 18 - Prob. 92SAECh. 18 - Prob. 93SAECh. 18 - Prob. 94SAECh. 18 - Prob. 95SAECh. 18 - Prob. 96SAECh. 18 - Prob. 97SAECh. 18 - Prob. 98SAECh. 18 - Prob. 99SAECh. 18 - Prob. 100SAECh. 18 - Prob. 101SAECh. 18 - Prob. 102SAECh. 18 - Prob. 103SAECh. 18 - Prob. 104SAECh. 18 - Prob. 105SAECh. 18 - Prob. 106SAECh. 18 - Will Agl(s) precipitate from a solution with [[Ag...Ch. 18 - Prob. 108SAECh. 18 - Appendix describes a useful study aid known as...
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- How do the concentrations of Ag+ and CrO42- in a saturated solution above 1.0 g of solid Ag2CrO4 Change when 100 g of solid Ag2CrO4 is added to the system? Explain.arrow_forwardA 1.0-L solution that is 4.2 M in ammonia is mixed with 26.7 g of ammonium chloride. a What is the hydroxide-ion concentration of this solution? b 0.075 mol of MgCl2 is added to the above solution. Assume that there is no volume change. After Mg(OH)2 has precipitated, what is the molar concentration of magnesium ion? What percent of the Mg2+ is removed from solution?arrow_forwardHow would the solubility of calcium fluoride be affected by the presence of fluoride ion from another source? What is the solubility of calcium fluoride in a saturated solution of barium fluoride? How does this compare with the value of the solubility of calcium fluoride found in Example 17.4? Is this what you expect?arrow_forward
- A solution is 1.5 104 M Zn2 and 0.20 M HSO4. The solution also contains Na2SO4. What should be the minimum molarity of Na2SO4 to prevent the precipitation of zinc sulfide when the solution is saturated with hydrogen sulfide (0.10 M H2S)?arrow_forwardA solution is made up by adding 0.632 g of barium nitrate and 0.920 g of lanthanum nitrate, to La(NO3)3 enough water to make 0.500 L of solution. Solid sodium iodate, NalO3, is added (without volume change) to the solution. (a) Which salt will precipitate first? La(IO3)3 (Ksp=7.501012) or BAIO3 (Ksp=4.0109)? (b) What is [IO3-] when the salt in (a) first begins to precipitate?arrow_forwardA volume of 50 mL of 1.8 M NH3 is mixed with an equal volume of a solution containing 0.95 g of MgCl2. What mass of NH4Cl must be added to the resulting solution to prevent the precipitation of Mg(OH)2?arrow_forward
- What must be the concentration of chromate ion in order to precipitate strontium chromate, SrCrO4, from a solution that is 0.0034 M Sr2+?arrow_forwardWhat is the difference between the ion product, Q, and the solubility product, Ksp? What happens when Q Ksp? Q Ksp? Q = Ksp?arrow_forwardA saturated solution of a slightly soluble electrolyte in contact with some of the solid electrolyte is said to be a system in equilibrium. Explain. Why is such a system called a heterogeneous equilibrium?arrow_forward
- Consider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2 F(aq) (a) Calculate K for the reaction. (b) Will BaSO4 precipitate if Na2SO4 is added to a saturated solution of BaF2?arrow_forwardA solution contains 0.00740 M calcium ion. A concentrated sodium fluoride solution is added dropwise to precipitate calcium fluoride (assume no volume change). a At what concentration of F does precipitate start to form? b When [F] = 9.5 104 M, what is the calcium-ion concentration? What percentage of the calcium ion has precipitated?arrow_forwardAn analytical chemist has a solution containing chloride ion, Cl. She decides to determine the amount of chloride ion in the solution by titrating 50.0 mL of this solution by 0.100 M AgNO3. As a way to indicate the endpoint of the titration, she added 1.00 g of potassium chromate, K2CrO4 (see Figure 17.5). As she slowly added the silver nitrate to the solution, a white precipitate formed. She continued the titration, with more white precipitate forming. Finally, the solution turned red, from another precipitate. The volume of the solution at this point was 60.3 mL. How many moles of chloride ion were there in the original solution? How many moles of chloride ion were there in the final solution? You may make any reasonable approximations.arrow_forward
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