1 Matter: Its Properties And Measurement 2 Atoms And The Atomic Theory 3 Chemical Compounds 4 Chemical Reactions 5 Introduction To Reactions In Aqueous Solutions 6 Gases 7 Thermochemistry 8 Electrons In Atoms 9 The Periodic Table And Some Atomic Properties 10 Chemical Bonding I: Basic Concepts 11 Chemical Bonding Ii: Valence Bond And Molecular Orbital Theories 12 Intermolecular Forces: Liquids And Solids 13 Spontaneous Change: Entropy And Gibbs Energy 14 Solutions And Their Physical Properties 15 Principles Of Chemical Equilibrium 16 Acids And Bases 17 Additional Aspects Of Acid–base Equilibria 18 Solubility And Complex-ion Equilibria 19 Electrochemistry 20 Chemical Kinetics 21 Chemistry Of The Main-group Elements I: Groups 1, 2, 13, And 14 22 Chemistry Of The Main-group Elements Ii: Groups 18, 17, 16, 15, And Hydrogen 23 The Transition Elements 24 Complex Ions And Coordination Compounds 25 Nuclear Chemistry 26 Structures Of Organic Compounds 27 Reactions Of Organic Compounds expand_more
Chapter Questions expand_more
Problem 1E: Write K10 expressions for the following equilibria. For example, for the reaction... Problem 2E: Write solubility equilibrium equations that are described by the following K10 expressions. For... Problem 3E: The following K10 values ate found in a handbook. Write the solubility product expression to which... Problem 4E: Calculate the aqueous solubility, in moles per liter, of each of the following. BaCrO4,K10=1.21010... Problem 5E Problem 6E: Which of the following saturated aqueous solutions would have the highest [Mg2+] ? Explain. MgCO2;... Problem 7E: Fluoridated drinking water contains about 1 part per million (ppm) of F is CaF2 sufficiently soluble... Problem 8E: In the qualitative cation analysis procedure, Bi2+ is detected by the appearance of the white... Problem 9E Problem 10E: A 725mL sample of a saturated solution of calcium oxalate, CaC2O4 , at 95C . How many milligrams of... Problem 11E: A 25.00mL sample of a clear saturated solution of Pbl2 requires 13.3mL of a certain AgNO2(aq) for... Problem 12E: A 250 mL sample of saturated CaC2O4 (aq) requires 4.8 mL of 0.00134 KMnO4(aq) for its titration ran... Problem 13E Problem 14E Problem 15E: Calculate the molar solubility of Mg(OH)2(K10=1.81011) in (a) pure water, (b) 00862 M MgCI2. (C)... Problem 16E: How would you expect the presence of the following solutes to affect the molar solubility of CaCO2... Problem 17E Problem 18E: Describe the effect of the salt NNO2 on the solubility of Agl in water, and explain why is different... Problem 19E: A 0.150 M Na2SO4 , solution that is saturated with Ag2SO4 , has [Ag+]=9.7102M . What is the value of... Problem 20E: It 100.0 mL of 0. 0025 U Na2SO4(aq) is saturated with CaSO4 , how many grams of CaSO4 would be... Problem 21E: What [Pb2+] should be maintained in Pb( NO2)2(aq) to produce a solubility of 1.5104molpbl2/L when... Problem 22E: What [l-] should be maintained in Kl(aq) to produce a solubility of 1.5103 mol Pbl2 when Pbl2 is... Problem 23E: Can the solubility of Ag2CrO4 be lowered to 5.0104 mol Ag2CrO4/L by using CrO42 as the common ion?... Problem 24E Problem 25E Problem 26E Problem 27E: Will prectiation of MgF2(s) occur if a 22.5 mg sample of MgCl26H2 is added to 325 mL of 0035 M KF? Problem 28E: Will pbCl2 precitate when 155mL of 0.016M KCl(aq) are added to 245 mL of 0.175 0.175MPb( NO2)2(aq) ? Problem 29E: What is the minimum pH at which Cd(OH)2(s) will prcipitate from a solution that is 0.0055 M in... Problem 30E: What is the minimum pH at which Cr(OH)2(s) will precipitate from a solution that is 0086 M m Cr2+... Problem 31E: Will precipitation occur in the following cases? 010mg NeCI s added to 1.0 Lot 010 M AgNO2(aq). One... Problem 32E Problem 33E Problem 34E Problem 35E: When 200.0 ml. of 0 350 N K2CrO4(aq) are added to 2000 mL of 0.0100 M AgNO2 (aq), what percentage of... Problem 36E: What percentage of the original Ag4 remains in solution when 175mL 0.0208M AgNO4 is added to 250mL... Problem 37E Problem 38E: The ancient Romans added calcium sulfate to wine to clarify and to remove dissolved lead. What is... Problem 39E Problem 40E Problem 41E: Kl(aq) is slowly added to a solution with [Pb2+]=[Ag4]=0.10M. For Pbl2 , K10=7.1102 ; for Agl... Problem 42E: A solution is 0010 M en both CrO42- and SO42 . To this solution, 0.50 M Pb ( NO2)2 (aq) is slowly... Problem 43E: An aqueous solution that 200 U m AgNO2 slowly added from a buret to an aqueous solution that is 0... Problem 44E: AgNO2(aq) is slowly added to a solution that is 0.250 M NaCI and also 0.0022 M KBr. Which anion will... Problem 45E: Which of the following solids is (are) more soluble in an acidic solution than in pure water: KCl,... Problem 46E: Which of the blowing solids is (are) more soluble in a basic solution than in pure water BaSO4 ,... Problem 47E: The solubility of Mg(OH)2 m a particualr buffer solution is 065 g/L What must be the pH of the... Problem 48E: To 0.350L of 0.150MNH2 is added 0.150 L of 0.100 M MgCl2 . How many grams of ( NH4)2SO4 should be... Problem 49E: For the equilibrium Al(OH)3(s)Al3+(aq)+3OH(aq)KSp=1.31033 What is the minimum pH at which Al(OH)2... Problem 50E: Will the following precipitates form under the given conditions? Pbl2(s) , from a solution that is... Problem 51E Problem 52E Problem 53E: In a solution that is 0.0500M in [Cu( CN)4]2 and 0.80M in free CN- ; the concentration of Cu is... Problem 54E: Calculate [Cu2+] in a 0.10M CuSO4(aq) solution that is also 6.0M in free NH2 . Cu2+(aq)+4NH3(aq)[Cu(... Problem 55E Problem 56E: A solution is 0.10 M in free NH2 ,0.10M in NH4Cl , and 0.015 M in [Cu( NH 2 )4]2+ precipitate from... Problem 57E: A 0.10 mol sample of AgNO2(s) is dissolved in 1.00L of 1.00 M NH2 . How many grams of Kl can be... Problem 58E: A solution is prepared at has [NH2]=1.00M and [Cl-]=0.100M . How many grams of AgNO2 can be... Problem 59E Problem 60E: A solution is 0.05 U m Cu2+ in Hg2+ , and in Mn2+ . Which sulfides will precipitate if the solution... Problem 61E Problem 62E Problem 63E: Suppose you did a group 1 qualitative cation analysis and treated the chloride precipitate with... Problem 64E Problem 65E Problem 66E Problem 67IAE Problem 68IAE: A handbook lists the solubility of CaHPO4 as 0.32g CaHPO42H2O/L and lists K101107... Problem 69IAE Problem 70IAE: What percentage of the Ba2+ in solution is precipitated as BaCO2(s) if equal volumes of 0.0020... Problem 71IAE Problem 72IAE Problem 73IAE Problem 74IAE: What is the solubility of MnS, in grams per liter, in a buffer solution that is... Problem 75IAE Problem 76IAE Problem 77IAE Problem 78IAE Problem 79IAE Problem 80IAE Problem 81IAE Problem 82IAE Problem 83IAE Problem 84IAE Problem 85IAE: A 2509 sample of Ag2SO4(s) added to a beaker containing 0.150 L of 0 025 PA BaCl2. Write an equation... Problem 86IAE Problem 87FP Problem 88FP: In the Mohr titration, Cl(aq) is titrated with AgNO3 in solutions that are pH=7. Thus it is suitable... Problem 89FP: The accompanying drawing suggests a series of manipulations starting with saturated Mg(OH)2(aq)... Problem 90SAE Problem 91SAE: Briefly describe each of the following ideas, methods, or phenomena (a) common-ion effect in... Problem 92SAE Problem 93SAE Problem 94SAE Problem 95SAE Problem 96SAE Problem 97SAE Problem 98SAE Problem 99SAE Problem 100SAE Problem 101SAE Problem 102SAE Problem 103SAE Problem 104SAE Problem 105SAE Problem 106SAE Problem 107SAE: Will Agl(s) precipitate from a solution with [[Ag ( CN )2]+]=0.012M , and [l-]=2.0M ? For Agl ,... Problem 108SAE Problem 109SAE: Appendix describes a useful study aid known as concept mapping Using the methods presented r... format_list_bulleted