(a) Interpretation: The curved-arrow mechanisms for the given reaction is to be drawn. Concept introduction: The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

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Answer 1

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Show how you would accomplish the following transformations. More than one step may be required. ow all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3CH2C-CN CH3 CH3.

Show how you would accomplish the following transformations. More than one step may be required. now all reagents and all intermediate structures [one ONLY] A. H Br H CH3 NHz CH3 CH3 B. CH3CH2C-Br CH3 CH3CH2C-CN CH3

Answer 2

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 3

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 4

Question

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

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Answer 5

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 6

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Answer 7

Chapter 18, Problem 18.78AP

Interpretation Introduction

(a)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of halogen atom attached to a carbon atom of electron-rich benzene ring by an incoming group is known as addition elimination reaction of aryl halides. The rate of this type of reaction depends on the incoming size of halide. The reactivity of fluoride substituted compound is highest.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The curved-arrow mechanisms for the given reaction is to be drawn.

Concept introduction:

The replacement of hydrogen atom attached to a carbon atom of electron-rich benzene ring by another electrophile is known as electrophilic aromatic substitution reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group on the aromatic ring. The ring deactivating group retards the electrophilic aromatic substitution reaction and ring activating group enhances the electrophilic aromatic substitution reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author illustrates the curved-arrow mechanisms for the given reaction. The rate of electrophilic aromatic substitution reaction depends on the substituted group of the aromatic ring.

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