The mechanism for the given aldol addition reaction, which is catalyzed by acid is to be drawn. Concept introduction: The aldol condensation reaction can take place under acidic conditions. The carbon nucleophile cannot be an enolate anion as it is strongly basic. Under acidic conditions, the nucleophile can be an enol which is nucleophilic at α carbon atom. The enol is produced by two steps of proton transfer which is also called tautomerization.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.66P

Interpretation Introduction

Interpretation:

The mechanism for the given aldol addition reaction, which is catalyzed by acid is to be drawn.

Concept introduction:

The aldol condensation reaction can take place under acidic conditions. The carbon nucleophile cannot be an enolate anion as it is strongly basic. Under acidic conditions, the nucleophile can be an enol which is nucleophilic at α carbon atom. The enol is produced by two steps of proton transfer which is also called tautomerization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Questions 4 and 5

For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.

Predict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.66P

Interpretation Introduction

Interpretation:

The mechanism for the given aldol addition reaction, which is catalyzed by acid is to be drawn.

Concept introduction:

The aldol condensation reaction can take place under acidic conditions. The carbon nucleophile cannot be an enolate anion as it is strongly basic. Under acidic conditions, the nucleophile can be an enol which is nucleophilic at α carbon atom. The enol is produced by two steps of proton transfer which is also called tautomerization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.66P

Interpretation Introduction

Interpretation:

The mechanism for the given aldol addition reaction, which is catalyzed by acid is to be drawn.

Concept introduction:

The aldol condensation reaction can take place under acidic conditions. The carbon nucleophile cannot be an enolate anion as it is strongly basic. Under acidic conditions, the nucleophile can be an enol which is nucleophilic at α carbon atom. The enol is produced by two steps of proton transfer which is also called tautomerization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 18, Problem 18.66P

Interpretation Introduction