(a) Interpretation: The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated. Concept introduction: Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

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Answer 1

Question

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

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Shown below is the mechanism presented for the formation of biasplatin in reference 1 from the Background and Experiment document. The amounts used of each reactant are shown. Either draw or describe a better alternative to this mechanism. (Note that the first step represents two steps combined and the proton loss is not even shown; fixing these is not the desired improvement.) (Hints: The first step is correct, the second step is not; and the amount of the anhydride is in large excess to serve a purpose.)

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Draw a reasonable mechanism for the following reaction:

Answer 2

Question

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

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Answer 3

Question

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

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Answer 4

Question

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

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Answer 5

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Answer 6

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Answer 7

Chapter 18, Problem 18.48AP

Interpretation Introduction

(a)

Interpretation:

The product formed on reaction of 1-hexene with allyl alcohol in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The product formed on reaction of 1-hexene with 2-methylpropene in presence of Grubbs G2 catalyst is to be stated.

Concept introduction:

Grubbs catalyst is a complex made up of transition metal and carbine. Interchange of double bonds takes places when alkenes are treated with Grubbs catalyst. The metal atom in this catalyst is ruthenium and a mixture of products is formed in this reaction. Olefin metathesis is a process in which there is exchange of substituents between different olefins.

Answer 10

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains that Grubbs catalyst is a complex made up of transition metal and carbine.

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