(a) Interpretation: The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated. Concept introduction: The S N 1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster S N 1 reaction.

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Answer 1

Question

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

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LTS Solid: AT=Te-Ti Trial 1 Trial 2 Trial 3 Average ΔΗ Mass water, g 24.096 23.976 23.975 Moles of solid, mol 0.01763 001767 0101781 Temp. change, °C 2.9°C 11700 2.0°C Heat of reaction, J -292.37J -170.473 -193.26J AH, kJ/mole 16.58K 9.647 kJ 10.85 kr 16.58K59.64701 KJ mol 12.35k Minimum AS, J/mol K 41.582 mol-k Remember: q = mCsAT (m = mass of water, Cs=4.184J/g°C) & qsin =-qrxn & Show your calculations for: AH in J and then in kJ/mole for Trial 1: qa (24.0969)(4.1845/g) (-2.9°C)=-292.37J qsin = qrxn = 292.35 292.37J AH in J = 292.375 0.2923kJ 0.01763m01 =1.65×107 AH in kJ/mol = = 16.58K 0.01763mol mol qrx Minimum AS in J/mol K (Hint: use the average initial temperature of the three trials, con Kelvin.) AS=AHIT (1.65×10(9.64×103) + (1.0 Jimai

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Answer 2

Question

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

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Answer 3

Question

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

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Answer 4

Question

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

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Answer 5

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Answer 6

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Answer 7

Chapter 18, Problem 18.42P

Interpretation Introduction

(a)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The ether that would not readily cleave with concentrated HBr and heat is to be predicted. The products and mechanism for the ether that would readily cleave are to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The more stable carbocation gives faster SN1 reaction.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains that the ether that would not readily cleave with concentrated HBr and heat is to be predicted.

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Chapter 18 Solutions