(a) Interpretation: The increasing order of S N 1 − E 1 reaction of the given compounds along with the reason is to be stated. Concept introduction: The S N 1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in S N 1 and E 1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In S N 1 pathway, the next step is substitution while in E 1 pathway, the next step is elimination.According to Zaitsev rule, in E 1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

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Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

Question

Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

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Answer 3

Question

Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

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Answer 4

Question

Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

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Answer 5

Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Answer 6

Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Answer 7

Chapter 18, Problem 18.3P

Interpretation Introduction

(a)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The increasing order of SN1−E1 reaction of the given compounds along with the reason is to be stated.

Concept introduction:

The SN1 reaction is a nucleophilic substitution reaction in which the substitution of nucleophile takes place. This reaction takes place in two steps. This generates a carbocation intermediate in the reaction. The first step is common in SN1 and E1 reactions i.e. the heterolysis of carbon halogen bond to form a carbocation. In SN1 pathway, the next step is substitution while in E1 pathway, the next step is elimination.According to Zaitsev rule, in E1 reactions, the more substituted or more alkylated alkene is the major product as it is more stable.

Answer 10

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Answer 13

Ch. 18 - Prob. 18.1P Ch. 18 - Prob. 18.2P Ch. 18 - Prob. 18.3P Ch. 18 - Prob. 18.4P Ch. 18 - Prob. 18.5P Ch. 18 - Prob. 18.6P Ch. 18 - Prob. 18.7P Ch. 18 - Prob. 18.8P Ch. 18 - Prob. 18.9P Ch. 18 - Prob. 18.10P

Solution Summary: The author explains the increasing order of S_TextN1- TextE1, which depends on the stability of carbocation and the leaving group ability.

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Chapter 18 Solutions