PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Chapter 18, Problem 18.39UKC

(a)

Interpretation Introduction

Interpretation:

Number of molecules of acetyl CoA formed from catabolism of fatty acid below has to be determined.

Concept Introduction:

Fatty acid catabolism by β-oxidation produces two-carbon acetyl CoA units.  Catabolism of fatty acids starts from conversion of fatty acids into acyl CoA. This process consumes 2 units of ATP. In this process, number of acetyl CoA molecules produced is equal to half of total number of carbon present in fatty acid. Also, number of cycles is 1 fewer than total number of molecules of acetyl CoA formed.

Number of NADH and FADH2 molecules produced in fatty acid catabolism by β-oxidation are equal to number of cycles required to completely catabolize fatty acids.

(b)

Interpretation Introduction

Interpretation:

Number of β-oxidation cycles required in complete catabolism of fatty acid below has to be determined.

Concept Introduction:

Refer to part (a).

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Questions 4 and 5
For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.
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