PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 18, Problem 18.15E
Interpretation Introduction

Interpretation:

The electronic partition function for H2O(g) at 373K is to be calculated.

Concept introduction:

The point at which the bond between the two atoms become nonexistent and the molecule exists as two separated atoms is known as dissociation limit. The relation between D0 and De is given by the formula,

D0=De12hv

Where,

D0 represents dissociation energy.

h is the Plank’s constant.

v is vibrational frequency.

De is the minimum potential energy of ground electronic state with respect to the zero points.

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For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.
Predict the major organic product(s), if any, of the following reactions.  Assume all reagents are in excess unless otherwise indicated.

Chapter 18 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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