PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
Question
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Chapter 18, Problem 18.55E
Interpretation Introduction

(a)

Interpretation:

The equivalent force constant is to be calculated.

Concept introduction:

The Hook’s law states that the strain produced in a solid is directly proportional to the applied force on it. The classical harmonic oscillator shows repetitive motion. It follows the Hook’s law. The Hook’s law is given by,

F=Kx

Where,

F is the force.

K is the spring constant.

x is the deformation.

Interpretation Introduction

(b)

Interpretation:

The wavenumber of the light is to be calculated.

Concept introduction:

The relation between wavenumber and frequency is given by the formula,

ν=cv¯

Where,

c is the speed of light.

v¯ is the wavenumber.

ν is the frequency.

Interpretation Introduction

(c)

Interpretation:

Whether the answer of part b agrees with the generality that many solid materials are very good absorbers of low-energy infrared light is to be stated.

Concept introduction:

The relation between wavenumber and frequency is given by the formula,

ν=cv¯

Where,

c is the speed of light.

v¯ is the wavenumber.

ν is the frequency.

The relation between wavenumber and energy is given by the formula,

E=hcv¯

Where,

h is the planck’s constant.

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3. ^14N^16O (the superscripts represent the atomic mass number)  (a) NO molecules rotate at an angular velocity of 2.01x10^12 rev/s, at the quantized rotational state with the rotational quantum number J of 3. Calculate the bond length of NO molecules. (b) Can NO molecules rotate under light irradiation? Explain your answer. (c) Calculate the effective force constant of the vibrational mode of NO at a frequency of 5.63x10^13 Hz measured by the infrared absorption spectrum. (d) NO has a bond energy of 6.29 eV. Applying the parabolic approximation to estimate the longest distance in which N and O atoms can be stretched before the dissociation of the molecular bond
6. The NaH molecule undergoes a rotational transition from J=0 to J=1 when it absorbs a photon of frequency 2.94×10' Hz. What is the equilibrium bond length of the molecule?
Emission of microwave radiation from the J = 10 transition of a molecule has been detected at 88.63 GHz from a region of interstellar space in which there is evidence of thermal equilibrium and a temperature of around 50 K. Estimate the frequency and relative intensity of the J = 2 → 1 transition of the same molecule.

Chapter 18 Solutions

PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.

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