Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 18, Problem 16P
Interpretation Introduction
Interpretation: The structural formula for the monophosphate ester formed by the reaction of 1,3-dihydroxy-2-propanone and phosphoric acid should be drawn.
Concept introduction:The formula by which the arrangement of atoms within a molecule is represented and the connection of atoms are shown by line (or lines) which represent a
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 18 Solutions
Introduction to General, Organic and Biochemistry
Ch. 18.1 - Prob. 18.1QCCh. 18.4 - Problem 19-2 Complete the equation for each...Ch. 18.4 - Prob. 18.3QCCh. 18 - Prob. 1PCh. 18 - Write the IUPAC name for each compound.Ch. 18 - Prob. 3PCh. 18 - Prob. 4PCh. 18 - Prob. 5PCh. 18 - Prob. 6PCh. 18 - 0 Complete the equations for these reactions.
Ch. 18 - Prob. 8PCh. 18 - Prob. 9PCh. 18 - Prob. 10PCh. 18 - Prob. 11PCh. 18 - Prob. 12PCh. 18 - 6 Why are Dacron and Mylar referred to as...Ch. 18 - 7 What type of structural feature do the...Ch. 18 - Prob. 15PCh. 18 - Prob. 16PCh. 18 - 0 Show how triphosphoric acid can form from three...Ch. 18 - 1 Write an equation for the hydrolysis of...Ch. 18 - Prob. 19PCh. 18 - (The Pyrethrins-Natural Insecticides of Plant...Ch. 18 - Prob. 21PCh. 18 - Prob. 22PCh. 18 - Prob. 23PCh. 18 - Prob. 24PCh. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - Prob. 31PCh. 18 - Prob. 32PCh. 18 - Prob. 33PCh. 18 - Prob. 34PCh. 18 - Prob. 35PCh. 18 - Prob. 36PCh. 18 - Prob. 37PCh. 18 - Prob. 38PCh. 18 - Prob. 39PCh. 18 - Prob. 40PCh. 18 - Prob. 41PCh. 18 - Prob. 42PCh. 18 - Prob. 43PCh. 18 - Prob. 44PCh. 18 - Prob. 45PCh. 18 - Prob. 46P
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