Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 18, Problem 12P
Interpretation Introduction

Interpretation:

To draw short sections of two parallel chains of nylon-66(each running in the same direction) and if it is possible to align them in such a way that there is hydrogen bonding between the N-H groups of one chain and the C=O groups of the parallel chain should be explained.

Concept Introduction:

A hydrogen bond is formed by a partial electrostatic attraction between hydrogen (H) atom attached to an electronegative atom (nitrogen (N), oxygen (O), or fluorine (F)) and other electronegative atom and lone pair present in the vicinity of it.

Introduction to General, Organic and Biochemistry, Chapter 18, Problem 12P

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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