Introduction to General, Organic and Biochemistry
Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Chapter 18, Problem 46P
Interpretation Introduction

(a)

Interpretation:

For the below diagram draw the structural formula and write the names for the monomer units present in each:

Introduction to General, Organic and Biochemistry, Chapter 18, Problem 46P , additional homework tip  1

Concept Introduction:

Biodegradable polymers are the specific kind of polymer which can be broken down after its proposed purpose to result within natural byproducts like inorganic salts, gases, biomass and water. These polymers can be found naturally as well as can be made up synthetically as well. Their breakdown mechanism and properties are found out through their particular structure.

Interpretation Introduction

(b)

Interpretation:

For the below diagram draw the structural formula and write the names for the monomer units present in each:

Introduction to General, Organic and Biochemistry, Chapter 18, Problem 46P , additional homework tip  2

Concept Introduction:

Biodegradable polymers are the specific kind of polymer which can be broken down after its proposed purpose to result within natural byproducts like inorganic salts, gases, biomass and water. These polymers can be found naturally as well as can be made up synthetically as well. Their breakdown mechanism and properties are found out through their particular structure.

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19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+
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