a) Interpretation: Starting from testosterone how to prepare the compound shown is to be shown. Concept introduction: Pyridiniumchlorochromate in dichloromethane oxidizes 1 0 alcohols to aldehydes and 2 0 alcohols to ketones . To show: Starting from testosterone how to prepare the compound shown is to be stated.

Question

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

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How many signals do you expect in the H NMR spectrum for this molecule? Br Br Write the answer below. Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H atoms that would contribute to the same signal as the H already highlighted red. Note for advanced students: In this question, any multiplet is counted as one signal. Number of signals in the 'H NMR spectrum. For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in top molecule For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute to the same signal as the H atom already highlighted red. If no other H atoms will contribute, check the box at right. No additional Hs to color in bottom molecule

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 6

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Answer 7

Chapter 17.SE, Problem 63AP

Interpretation Introduction

a)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be shown.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones.

To show:

Starting from testosterone how to prepare the compound shown is to be stated.

Answer 8

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 9

Interpretation Introduction

b)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 10

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 11

Interpretation Introduction

c)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

Pyridiniumchlorochromate in dichloromethane oxidizes 1⁰ alcohols to aldehydes and 2⁰ alcohols to ketones. H₂, Pd/C can reduce the double bond in a compound without affecting aldehydic or keto group present in the compound.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 12

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 13

Interpretation Introduction

d)

Interpretation:

Starting from testosterone how to prepare the compound shown is to be stated.

Concept introduction:

LiAlH₄ in ether reduces unsaturated aldehydes, acids and esters to 1⁰ alcohols. It reduces ketones to 2⁰ alcohols. The double bond remains unaffected during the reduction. The double bond can be reduced using H₂, Pd/C.

To state:

Starting from testosterone how to prepare the compound shown.

Answer 14

Expert Solution & Answer

Answer 15

Expert Solution & Answer

Answer 16

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Answer 17

Ch. 17.1 - Give IUPAC names for the following compounds:Ch. 17.1 - Prob. 2P Ch. 17.2 - The following data for isomeric four-carbon...Ch. 17.2 - Rank the following substances in order of...Ch. 17.2 - Prob. 5P Ch. 17.3 - Prob. 6P Ch. 17.4 - What reagent would you use to accomplish each of...Ch. 17.4 - Prob. 8P Ch. 17.5 - Prob. 9P Ch. 17.5 - Prob. 10P

Solution Summary: The author explains how the compound can be prepared by oxidizing testosterone using pyridiniumchlorochromate in dichloromethane.

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Chapter 17 Solutions