a.
Interpretation:
The overall effect on the reaction equilibrium on increasing temperature and volume needs to be explained.
Concept introduction :Le Chatelier principle states that a system at equilibrium when subjected to changes in the system adjusts it self to attain the equilibrium state again.
a.
Answer to Problem 77A
The equilibrium will shift to the left and reverse reaction will be favored.
Explanation of Solution
Since amount of product is more than amount of reactant, increasing volume will decrease the concentration of reactant more. Also, the reaction is exothermic, so increasing the temperature will favour the reverse reaction in accordance with Le Chatelier principle.
b.
Interpretation:
The overall effect on the reaction equilibrium due to increase in temperature and volume needs to be explained.
Concept introduction:
Le Chatelier principle states that a system at equilibrium when subjected to changes in the system adjusts it self to attain the equilibrium state again.
b.
Answer to Problem 77A
The equilibrium will shift to the right and forward reaction will be favored.
Explanation of Solution
Since amount of product is equal to the amount of reactant, increasing volume will decrease the concentration of reactant and product equally which will nullify each other’s effects. Also, the reaction is endothermic, so increasing the temperature will favour the forward reaction in accordance with Le Chatelier principle.
Chapter 17 Solutions
Glencoe Chemistry: Matter and Change, Student Edition
Additional Science Textbook Solutions
Brock Biology of Microorganisms (15th Edition)
The Cosmic Perspective (8th Edition)
Biology: Life on Earth (11th Edition)
Microbiology: An Introduction
Campbell Biology in Focus (2nd Edition)
Genetic Analysis: An Integrated Approach (3rd Edition)
- Part 4: Provide a detailed retrosynthetic analysis and a plausible forward synthesis the following molecule. храдо ofarrow_forward3A: Starting with benzocyclobutene, synthesize the naphthalene derivative below.arrow_forward7. The addition of HBr to 2,5-dimethyl-2,4-heptadiene gives the same product, A, at both low and high temperatures. Provide the structure of A and explain the kinetic and thermodynamic product are the same in this reaction. HBr -78°C or 60°C Aarrow_forward
- 3B: Convert the starting material into the chiral epoxytriol below. OH OH = OH OHarrow_forward3D: Convert the aromatic triketone to the 1,3,5-triethylcyclohexane shown below. ہوئےarrow_forwardIndicate how to find the energy difference between two levels in cm-1, knowing that its value is 2.5x10-25 joules.arrow_forward
- The gyromagnetic ratio (gamma) for 1H is 2.675x108 s-1 T-1. If the applied field is 1,409 T what will be the separation between nuclear energy levels?arrow_forwardChances Ad ~stract one 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $4th total Statistical pro 21 total 2 H A 2H 래 • 4H totul < 3°C-H werkest bund - abstraction he leads to then mo fac a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? рос 6 -વા J Number of Unique Mono-Chlorinated Products Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary H H-Clarrow_forwardWhat is the lone pair or charge that surrounds the nitrogen here to give it that negative charge?arrow_forward
- Last Name, Firs Statifically more chances to abstract one of these 6H 11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4 • 6H total $ 4th total 21 total 4H total ZH 2H Statistical H < 3°C-H werkst - product bund abstraction here leads to the mo favored a) (6pts) How many unique mono-chlorinated products can be formed and what are the structures for the thermodynamically and statistically favored products? Proclict 6 Number of Unique Mono-Chlorinated Products f Thermodynamically Favored Product Statistically Favored Product b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the formation of the thermodynamically favored product. Only draw the p-1 step. You do not need to include lone pairs of electrons. No enthalpy calculation necessary 'H H-Cl Waterfoxarrow_forward2. (a) Many main group oxides form acidic solutions when added to water. For example solid tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced chemical equation for this reaction. (b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-) and carbon monoxide. Write a balanced chemical equation for this reaction.arrow_forwardI find the solution way too brief and unsatisfactory as it does not clearly explain the solution provided in the problem.arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY