Organic Chemistry
11th Edition
ISBN: 9781118133576
Author: T. W. Graham Solomons, Craig Fryhle
Publisher: Wiley, John & Sons, Incorporated
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Textbook Question
Chapter 17, Problem 51P
Starting with 1-naphthol, suggest an alternative synthesis of the insecticide Sevin to the one given in Section 17.9A.
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יווי
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2H2S(g)+3O2(g)→2SO2(g)+2H2O(g)
A 1.2mol sample of H2S(g) is combined with excess O2(g), and the reaction goes to completion.
Question
Which of the following predicts the theoretical yield of SO2(g) from the reaction?
Responses
1.2 g
Answer A: 1.2 grams
A
41 g
Answer B: 41 grams
B
77 g
Answer C: 77 grams
C
154 g
Answer D: 154 grams
D
Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
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-26
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46
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115
10
1.0 0.9 0.8
0
-10
Chapter 17 Solutions
Organic Chemistry
Ch. 17 - Practice Problem 17.1 Give an IUPAC systematic...Ch. 17 - Prob. 2PPCh. 17 - PRACTICE PROBLEM
17.3 Which acid of each pair...Ch. 17 - Practice Problem 17.3 Write structural formulas...Ch. 17 - Practice Problem 17.4
Show how each of the...Ch. 17 - Practice Problem 17.5
Show how you could prepare...Ch. 17 - Practice Problem 17.6
(a) Which of the carboxylic...Ch. 17 - Prob. 8PPCh. 17 - Prob. 9PPCh. 17 - Practice Problem 17.9
Esters can also be...
Ch. 17 - Prob. 11PPCh. 17 - Prob. 12PPCh. 17 - Practice Problem 17.12
What products would you...Ch. 17 - Practice Problem 17.13 (a) Provide the reagents...Ch. 17 - Prob. 15PPCh. 17 - Practice Problem 17.15 Using decarboxylation...Ch. 17 - Practice Problem 17.16 Diacyl peroxides, ,...Ch. 17 - Prob. 18PCh. 17 - Give an IUPAC systematic or common name for each...Ch. 17 - Prob. 20PCh. 17 - Prob. 21PCh. 17 - 17.21 What major organic product would you expect...Ch. 17 - Prob. 23PCh. 17 - Prob. 24PCh. 17 - Prob. 25PCh. 17 - Prob. 26PCh. 17 - 17.26 What products would you expect to obtain...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - 17.28 Indicate reagents that would accomplish each...Ch. 17 - Write structural formulas for the major organic...Ch. 17 - Prob. 31PCh. 17 - Prob. 32PCh. 17 - Prob. 33PCh. 17 - 17.33 On heating,...Ch. 17 - Prob. 35PCh. 17 - Prob. 36PCh. 17 - 17.36 Show how pentanoic acid can be prepared from...Ch. 17 - 17.37 The active ingredient of the insect...Ch. 17 - Prob. 39PCh. 17 - Prob. 40PCh. 17 - Give stereochemical formulas for compounds AQ:...Ch. 17 - 17.41 -Glyceraldehyde can be transformed into...Ch. 17 - Prob. 43PCh. 17 - 17.44 Cantharidin is a powerful vesicant that can...Ch. 17 - Prob. 45PCh. 17 - 17.44 Given here are the NMR spectra and carbonyl...Ch. 17 - Compound X (C7H12O4) is insoluble in aqueous...Ch. 17 - 17.45 Compound Y dissolves slowly when warmed...Ch. 17 - Prob. 49PCh. 17 - Prob. 50PCh. 17 - 17.52 Starting with 1-naphthol, suggest an...Ch. 17 - Suggest a synthesis of ibuprofen (Section 5.11)...Ch. 17 - Prob. 53PCh. 17 - Prob. 54PCh. 17 - Prob. 1LGPCh. 17 - Prob. 2LGPCh. 17 - Prob. 3LGPCh. 17 - Prob. 4LGPCh. 17 - Prob. 1QCh. 17 - 17.2 Which of the following would yield...Ch. 17 - 17.3 Which reagent would serve as the basis for a...Ch. 17 - Prob. 4QCh. 17 - Complete the following synthesis.Ch. 17 - 17.6 Which of these acids would undergo...
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