
Interpretation:
The detailed mechanisms of the given reactions are to be predicted.
Concept introduction:
A mechanism involves the collection of all those steps that occur in a reaction.
Ester formation occurs between
The amide bond contains a carbonyl group bonded to an amino group. The amide bond is a reaction product of carboxylic acid, acid chlorides or esters with primary
Hydrolysis of the cyanide group in acidic medium results in the formation of the carboxylic group. The reaction occurs in presence of mineral acid and proceeds via the formation of amide as an intermediate.

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Chapter 17 Solutions
Organic Chemistry
- For benzene, the ∆H° of vaporization is 30.72 kJ/mol and the ∆S° of vaporization is 86.97 J/mol・K. At 1.00 atm and 228.0 K, what is the ∆G° of vaporization for benzene, in kJ/mol?arrow_forwardThe reaction Q(g) + R(g) → Z(l) is shown to be exothermic. Which of the following is true concerning the reaction. it is spontaneous only at High T, it is spontaneous at low T it is nonspontaneous at all T it is spontanrous at all T. it is non spontaneous only at low T.arrow_forwardThe reaction Q(g) + R(g) → Z(l) is shown to be exothermic. Which of the following is true concerning the reactionarrow_forward
- Which of the following has the largest standard molar entropy, S° (298.15 K) He H2 NaCl KBr Hgarrow_forwardWhich of the following is true for a particular reaction if ∆G° is -40.0 kJ/mol at 290 K and –20.0 kJ/mol at 390 K?arrow_forwardWhat is the major product of the following reaction? O O OH OH 1. BH 2. H₂O₂, NaOH OH OHarrow_forward
- How many products are possible from the following reaction? Do not take into account stereoisomers. 01 04 03 O O O O 02 CH H₂SO4 heatarrow_forwardplease helparrow_forwardChoose the major product of the reaction with correct regio- and stereochemistry. Br2 H₂O O "Br Br & O 'Br OH Br 吡 O OH OH Br "OH Brarrow_forward
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