
Concept explainers
(a)
Interpretation:
The number of R-groups present in primary amide has to be given.
Concept Introduction:
Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.
Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are
One of the
Amides are also classified as primary, secondary, and tertiary amide.
Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.
Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.
Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.
(b)
Interpretation:
The number of R-groups present in tertiary amide has to be given.
Concept Introduction:
Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.
Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.
One of the carboxylic acid derivative is amide. In this the carboxyl
Amides are also classified as primary, secondary, and tertiary amide.
Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.
Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.
Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.
(c)
Interpretation:
The number of R-groups present in monosubstituted amide has to be given.
Concept Introduction:
Organic compounds are the important basis of life. They include gasoline, coal, dyes, and clothing fibers etc. The compounds that are obtained from living organisms are termed as organic compounds and those obtained from the earth are known as inorganic compounds. Organic compounds are found in earth also apart from living organisms. All the organic compounds contain the element carbon. Urea was synthesized in the laboratory which is an organic compound.
Organic compounds contain heteroatom also. Some of them are nitrogen, sulfur, oxygen etc. Nitrogen containing organic compounds are of two important types and they are amines, amides.
One of the carboxylic acid derivative is amide. In this the carboxyl
Amides are also classified as primary, secondary, and tertiary amide.
Primary amide is the one that has a nitrogen atom that is bonded to two hydrogen atoms. Primary amides are also known as unsubstituted amides.
Secondary amide is the one that has a nitrogen atom that is bonded to one hydrogen atom and one alkyl (or aryl) group. Secondary amides are also known as monosubstituted amides.
Tertiary amide is the one that has a nitrogen atom that is bonded to two alkyl (or aryl) groups. Tertiary amides are also known as disubstituted amides.

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Chapter 17 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
- give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
- As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will its major product: 2,0° with a new C-C bond as If this reaction will work, draw the major organic product or products you would expect in the drawing aree below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and desh bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new C-C bond, just check the box under the drawing area and leave it blank.arrow_forwardwrite the mechanism of the nucleophilic acyl substitution reaction, please give an examplearrow_forwardThe compound in the figure is reacted with 10 n-butyllihium, 2° propanone, and 3º H2O. Draw and name the products obtained. SiMe3arrow_forward
- Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage LearningGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,


