
Concept explainers
(a)
Interpretation:
Structure of missing substance in the given reaction that involves amides has to be drawn.
Concept Introduction:
Amides are synthesized using amidification reaction. This involves a reaction between
(a)

Answer to Problem 17.138EP
Structure of the missing substance is,
Explanation of Solution
Given reaction is,
The starting material is a carboxylic acid and a primary amine. The product obtained on amidification reaction between carboxylic acid and a primary amine is a secondary amide. This is formed by the loss of water molecule. The structure of the secondary amide that is formed can be given as,
The complete reaction can be given as,
Structure of the missing compound is drawn.
(b)
Interpretation:
Structure of missing substance in the given reaction that involves amides has to be drawn.
Concept Introduction:
Amides are synthesized using amidification reaction. This involves a reaction between amine and carboxylic acid. In this reaction, the
(b)

Answer to Problem 17.138EP
Structure of the missing substance is,
Explanation of Solution
Given reaction is,
As the nitrogen atom present in the above amide has two hydrogen atoms bonded to it and the amide is a primary amide. Primary amide is produced by the reaction of ammonia with carboxylic acid. The structure of carboxylic acid can be found as shown below,
Hydrogen atom has to be added to the amine part and
The complete reaction can be given as,
Structure of the missing compound is drawn.
(c)
Interpretation:
Structure of missing substance in the given reaction that involves amides has to be drawn.
Concept Introduction:
Amides are synthesized using amidification reaction. This involves a reaction between amine and carboxylic acid. In this reaction, the
(c)

Answer to Problem 17.138EP
Structure of the missing substance is,
Explanation of Solution
Given reaction is,
As the nitrogen atom present in the above amide has no hydrogen atoms bonded to it, the amide is a tertiary amide. Tertiary amide is produced by the reaction of secondary amine with carboxylic acid. The parent compound structures can be identified as shown below,
Hydrogen atom has to be added to the amine part and
The complete reaction can be given as,
Structure of the missing compound is drawn.
(d)
Interpretation:
Structure of missing substance in the given reaction that involves amides has to be drawn.
Concept Introduction:
Amides are synthesized using amidification reaction. This involves a reaction between amine and carboxylic acid. In this reaction, the
(d)

Answer to Problem 17.138EP
Structure of the missing substance is,
Explanation of Solution
Given reaction is,
As the nitrogen atom present in the above amide has one hydrogen atom bonded to it and the amide is a secondary amide. Secondary amide is produced by the reaction of primary amine with carboxylic acid. The structure of carboxylic acid is given and the structure of primary amine has to be found out.
Hydrogen atom has to be added to the amine part and
The complete reaction can be given as,
Structure of the missing compound is drawn.
Want to see more full solutions like this?
Chapter 17 Solutions
EBK GENERAL, ORGANIC, AND BIOLOGICAL CH
- For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. དྲ。 ✗MgBr ? O CI Will the first product that forms in this reaction create a new C-C bond? Yes No • ? Will the first product that forms in this reaction create a new CC bond? Yes No × : ☐ Xarrow_forwardPredict the major products of this organic reaction: OH NaBH4 H ? CH3OH Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. ☐ : Sarrow_forwardPredict the major products of this organic reaction: 1. LIAIHA 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. X : ☐arrow_forward
- For each reaction below, decide if the first stable organic product that forms in solution will create a new C - C bond, and check the appropriate box. Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below. Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions - just focus on the first stable product you expect to form in solution. NH2 tu ? ? OH Will the first product that forms in this reaction create a new CC bond? Yes No Will the first product that forms in this reaction create a new CC bond? Yes No C $ ©arrow_forwardAs the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule with a new C-C bond as its major product: 1. MgCl ? 2. H₂O* If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for example to distinguish between major products with different stereochemistry. If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. This reaction will not make a product with a new CC bond. G marrow_forwardIncluding activity coefficients, find [Hg22+] in saturated Hg2Br2 in 0.00100 M NH4 Ksp Hg2Br2 = 5.6×10-23.arrow_forward
- give example for the following(by equation) a. Converting a water insoluble compound to a soluble one. b. Diazotization reaction form diazonium salt c. coupling reaction of a diazonium salt d. indacator properties of MO e. Diazotization ( diazonium salt of bromobenzene)arrow_forward2-Propanone and ethyllithium are mixed and subsequently acid hydrolyzed. Draw and name the structures of the products.arrow_forward(Methanesulfinyl)methane is reacted with NaH, and then with acetophenone. Draw and name the structures of the products.arrow_forward
- 3-Oxo-butanenitrile and (E)-2-butenal are mixed with sodium ethoxide in ethanol. Draw and name the structures of the products.arrow_forwardWhat is the reason of the following(use equations if possible) a.) In MO preperation through diazotization: Addition of sodium nitrite in acidfied solution in order to form diazonium salt b.) in MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at low pH c.) In MO experiment: addition of sodium hydroxide solution in the last step to isolate the product MO. What is the color of MO at pH 4.5 d.) Avoiding not cooling down the reaction mixture when preparing the diazonium salt e.) Cbvcarrow_forwardA 0.552-g sample of an unknown acid was dissolved in water to a total volume of 20.0 mL. This sample was titrated with 0.1103 M KOH. The equivalence point occurred at 29.42 mL base added. The pH of the solution at 10.0 mL base added was 3.72. Determine the molar mass of the acid. Determine the Ka of the acid.arrow_forward
- Organic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningChemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning



