PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
2nd Edition
ISBN: 9781266811852
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 17, Problem 17.40AP
List three structural similarities in DNA and RNA.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
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171.0
21.6
172.0
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181.0
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183.0
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Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
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HAVENUMBERI -11
Chapter 17 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
Ch. 17.1 - Prob. 17.1PCh. 17.1 - Draw the structure of guanosine. Classify the...Ch. 17.1 - Prob. 17.3PCh. 17.1 - Give the name that corresponds to each...Ch. 17.1 - Which nucleic acid (DNA or RNA) contains each of...Ch. 17.1 - Label each statement about the compound...Ch. 17.1 - Identify each component as a base, nucleoside, or...Ch. 17.2 - Draw the structure of a dinucleotide formed by...Ch. 17.2 - Label the 5' end and the 3' end in each...Ch. 17.2 - Label each statement about the polynucleotide...
Ch. 17.3 - Write the complementary strand for each of the...Ch. 17.4 - What is the sequence of a newly synthesized DNA...Ch. 17.6 - Prob. 17.13PCh. 17.6 - Prob. 17.14PCh. 17.11 - Prob. 17.24PCh. 17 - Label each statement as pertaining to DNA, RNA, or...Ch. 17 - (a) Identify the base and monosaccharide in the...Ch. 17 - (a) Identify the base and monosaccharide in the...Ch. 17 - Consider the given dinucleotide. a. Identify the...Ch. 17 - Answer Problem 17.29 for the following...Ch. 17 - Fill in the codon, anticodon, or amino acid needed...Ch. 17 - Fill in the codon, anticodon, or amino acid needed...Ch. 17 - What is the difference between a gene and a...Ch. 17 - Prob. 17.38APCh. 17 - List three structural differences between DNA and...Ch. 17 - List three structural similarities in DNA and RNA.Ch. 17 - Prob. 17.41APCh. 17 - Prob. 17.42APCh. 17 - Give the name, abbreviation, or structure of each...Ch. 17 - Give the name, abbreviation, or structure of each...Ch. 17 - Classify each molecule as a nucleoside or...Ch. 17 - Draw the structure of the deoxyribonucleotide...Ch. 17 - Draw the structure of the ribonucleotide formed by...Ch. 17 - Describe in detail the DNA double helix with...Ch. 17 - Describe in detail the DNA double helix with...Ch. 17 - Write the sequence of the complementary strand of...Ch. 17 - Write the sequence of the complementary strand of...Ch. 17 - What is the sequence of the mRNA molecule...Ch. 17 - What is the sequence of the mRNA molecule...Ch. 17 - Considering each nucleotide sequence in an mRNA...Ch. 17 - Considering each nucleotide sequence in an mRNA...Ch. 17 - What is the difference between a point mutation...Ch. 17 - Consider the following mRNA sequence: CUU CAG CAC....Ch. 17 - Consider the following mRNA sequence: ACC UUA CGA....
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- 16. The proton NMR spectral information shown in this problem is for a compound with formula CioH,N. Expansions are shown for the region from 8.7 to 7.0 ppm. The normal carbon-13 spec- tral results, including DEPT-135 and DEPT-90 results, are tabulated: 7 J Normal Carbon DEPT-135 DEPT-90 19 ppm Positive No peak 122 Positive Positive cus и 124 Positive Positive 126 Positive Positive 128 No peak No peak 4° 129 Positive Positive 130 Positive Positive (144 No peak No peak 148 No peak No peak 150 Positive Positive してしarrow_forward3. Propose a synthesis for the following transformation. Do not draw an arrow-pushing mechanism below, but make sure to draw the product of each proposed step (3 points). + En CN CNarrow_forwardShow work..don't give Ai generated solution...arrow_forward
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Nucleic acids - DNA and RNA structure; Author: MEDSimplified;https://www.youtube.com/watch?v=0lZRAShqft0;License: Standard YouTube License, CC-BY