Concept explainers
Interpretation:
Base and monosaccharide in below nucleoside has to be identified. Also, its name has to be assigned.
Concept Introduction:
1. Nitrogen-containing base
2. Pentose sugar
3. Phosphate group
Nucleosides are named accordingly as follows:
1. Identify the type of sugar unit attached is ribose or deoxyribose. If in the structure of nucleoside there is an
2. Identify the name of the different nitrogen bases present in the molecule. There are two types of bases that are pyrimidine base and purine base.
(a). Pyrimidine base consists of one ring and is present in uracil, cytosine, and thymine.
(b). Purine base consists of two rings and is present in adenine and guanine.
3. Nucleosides with pyrimidine bases end with the suffix
Abbreviation is assigned with respect to the type of sugar. For ribose sugar, 3 letter abbreviation is used and for deoxyribose sugar, 4 letter abbreviation is used followed by d as a prefix.
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Chapter 17 Solutions
PRIN.OF GENERAL,ORGANIC+BIOLOG.CHEM.
- 1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forwardWrite the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward
- 3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward
- 2. Construct Lewis-dot structures, and draw VESPR models for the ions listed below. a) SiF5 (4 points) b) IOF4 (4 points)arrow_forward5. Complex anion [AuCl2]¯ belongs to Doh symmetry point group. What is the shape of this ion? (4 points)arrow_forward4. Assign the following molecules to proper point groups: Pyridine N 1,3,5-triazine N Narrow_forward
- 7. a) Under normal conditions (room temperature & atmospheric pressure) potassium assumes bcc lattice. Atomic radius for 12-coordinate K atom is listed as 235 pm. What is the radius of potassium atom under normal conditions? (3 points) b) Titanium metal crystallyzes in hcp lattice. Under proper conditions nitrogen can be absorbed into the lattice of titanium resulting in an alloy of stoichiometry TiNo.2. Is this compound likely to be a substitutional or an interstitial alloy? (Radius of Ti (12-coordinate) is 147 pm; radius of N atom is 75 pm. (3 points)arrow_forwardcan someone answer the questions and draw out the complete mechanismarrow_forwardPlease help, draw and me the proper mechanisms.arrow_forward
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