Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 17, Problem 17.18P
Interpretation Introduction

(a)

Interpretation:

The mechanism for formation of limonene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

Interpretation Introduction

(b)

Interpretation:

The curved arrow mechanism for the synthesis of carbocation intermediate from a geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units. Limonene contains a cyclic monoterpene unit. The oil extracted from citrus peels majorly contains limonene.

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(9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception tothe general ionization energy (IE) trend. For the two elements involved, answer the followingquestions. Be sure to cite sources for all physical data that you use.a. (2 pts) Identify the two elements and write their electronic configurations.b. (2 pts) Based on their configurations, propose a reason for the IE trend exception.c. (5 pts) Calculate effective nuclear charges for the last electron in each element and theAllred-Rochow electronegativity values for the two elements. Can any of these valuesexplain the IE trend exception? Explain how (not) – include a description of how IErelates to electronegativity.
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