(a) Interpretation: The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated. Concept introduction: Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

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Answer 1

Question

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

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2) There are many forms of cancer, all of which involve abnormal cell growth. The growth and production of cells, called cell proliferation, is known to involve an enzyme called protein farnesyltransferase (PFTase). It is thought that inhibitors pf PFTase may be useful as anticancer drugs. The following molecule showed moderate activity as a potential PFTase inhibitor. Draw all stereoisomers of this compound. HO OH

Considering rotation around the bond highlighted in red, draw the Newman projection for the most stable and least stable conformations when viewed down the red bond in the direction of the arrow. Part 1 of 2 H₁₂C H H Draw the Newman projection for the most stable conformation. Select a template to begin. Part 2 of 2 Draw the Newman projection for the least stable conformation. G 心

Answer 2

Question

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

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Answer 3

Question

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

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Answer 4

Question

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

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Answer 5

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Answer 6

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Answer 7

Chapter 17, Problem 17.19P

Interpretation Introduction

(a)

Interpretation:

The mechanism for synthesis of farnesol from geranyl pyrophosphate is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism for synthesis of α−pinene from the given carbocation is to be stated.

Concept introduction:

Isoprene unit contains five carbon atoms. The carbon atoms of isoprene unit are connected by sigma bond or pi bond. Terpenes and terpenoids contain unequal number of isoprene units.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 17 - Prob. 17.1P Ch. 17 - Prob. 17.2P Ch. 17 - Prob. 17.3P Ch. 17 - Prob. 17.4P Ch. 17 - Prob. 17.5P Ch. 17 - Prob. 17.6P Ch. 17 - Prob. 17.7P Ch. 17 - Prob. 17.8P Ch. 17 - Prob. 17.9P Ch. 17 - Prob. 17.10P

Solution Summary: The author explains the mechanism for synthesis of farnesol from geranyl pyrophosphate.

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Chapter 17 Solutions