Concept explainers
Interpretation:
The boiling point of acetic acid is higher than that of its methyl ester even through acetic acid has a lower molecular weight. The factors behind this has to be given.
Concept introduction:
The boiling points of carboxylic acids are higher than those of alcohol or
Intermolecular hydrogen bonding will increase the boiling point of an organic compound.
Carboxylic acids can form dimers in which hydrogen bonds form between two carboxyl groups this will also increase their boiling point.
Increasing order of boiling point of some organic compounds with similar molecular weight is shown below,
The better hydrogen bond capability of a molecule will increase its boiling points.
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