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OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
11th Edition
ISBN: 9781305673939
Author: Darrell Ebbing; Steven D. Gammon
Publisher: Cengage Learning US
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Chapter 17, Problem 17.114QP
How would the solubility of calcium fluoride be affected by the presence of fluoride ion from another source? What is the solubility of calcium fluoride in a saturated solution of barium fluoride? How does this compare with the value of the solubility of calcium fluoride found in Example 17.4? Is this what you expect?
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Chapter 17 Solutions
OWLv2 for Ebbing/Gammon's General Chemistry, 11th Edition, [Instant Access], 1 term (6 months)
Ch. 17.1 - Give solubility product expressions for the...Ch. 17.1 - Silver ion may be recovered from used photographic...Ch. 17.1 - Lead(II) arsenate, Pb3(AsO4)2, has been used as an...Ch. 17.1 - Prob. 17.4ECh. 17.1 - Prob. 17.1CCCh. 17.2 - a. Calculate the molar solubility of barium...Ch. 17.2 - Suppose you have equal volumes of saturated...Ch. 17.2 - Prob. 17.3CCCh. 17.3 - Anhydrite is a mineral composed of CaSO4 (calcium...Ch. 17.3 - A solution of 0.00016 M lead(II) nitrate,...
Ch. 17.4 - Which salt would have its solubility more affected...Ch. 17.4 - If you add a dilute acidic solution to a mixture...Ch. 17.5 - What is the concentration of Cu2+(aq) in a...Ch. 17.6 - Will silver iodide precipitate from a solution...Ch. 17.6 - What is the molar solubility of AgBr in 1.0 M...Ch. 17 - Suppose the molar solubility of nickel hydroxide....Ch. 17 - Explain why calcium sulfate is less soluble in...Ch. 17 - What must be the concentration of silver ion in a...Ch. 17 - Prob. 17.4QPCh. 17 - Explain why barium fluoride dissolves in dilute...Ch. 17 - Prob. 17.6QPCh. 17 - Prob. 17.7QPCh. 17 - Prob. 17.8QPCh. 17 - Prob. 17.9QPCh. 17 - Prob. 17.10QPCh. 17 - Prob. 17.11QPCh. 17 - Write the solubility product expression for the...Ch. 17 - What is the molar solubility of calcium oxalate,...Ch. 17 - Prob. 17.14QPCh. 17 - Solubility and Solubility Product You put 0.10-mol...Ch. 17 - Solubility Equilibria Consider three hypothetical...Ch. 17 - Which compound in each of the following pairs of...Ch. 17 - Prob. 17.18QPCh. 17 - You are given a saturated solution of lead(II)...Ch. 17 - Which of the following pictures best represents a...Ch. 17 - Which of the following pictures best represents an...Ch. 17 - Prob. 17.22QPCh. 17 - Prob. 17.23QPCh. 17 - Prob. 17.24QPCh. 17 - Use the solubility rules (Table 4.1) to decide...Ch. 17 - Use the solubility rules (Table 4.1) to decide...Ch. 17 - Write solubility product expressions for the...Ch. 17 - Write solubility product expressions for the...Ch. 17 - Prob. 17.29QPCh. 17 - The solubility of magnesium oxalate, MgC2O4, in...Ch. 17 - The solubility of cobalt(II) iodate in water is...Ch. 17 - Prob. 17.32QPCh. 17 - The pH of a saturated solution of copper(II)...Ch. 17 - A solution saturated in calcium hydroxide...Ch. 17 - Strontianite (strontium carbonate) is an important...Ch. 17 - Magnesite (magnesium carbonate, MgCO3) is a common...Ch. 17 - What is the solubility of PbF2 in water? The Ksp...Ch. 17 - What is the solubility of strontium iodate,...Ch. 17 - What is the solubility (in grams per liter) of...Ch. 17 - What is the solubility (in grams per liter) of...Ch. 17 - The solubility of magnesium fluoride, MgF2, in...Ch. 17 - The solubility of silver sulfate, Ag2SO4, in water...Ch. 17 - What is the solubility (in grams per liter) of...Ch. 17 - Calculate the molar solubility of strontium...Ch. 17 - From each of the following ion concentrations in a...Ch. 17 - From each of the following ion concentrations in a...Ch. 17 - Lead(II) chromate, PbCrO4, was used as a yellow...Ch. 17 - Lead sulfate PbSO4, was used as a white paint...Ch. 17 - The following solutions are mixed: 1.0 L of...Ch. 17 - A 45-mL sample of 0.015 M calcium chloride, CaCl2,...Ch. 17 - A 45.0-mL sample of 0.0015 M BaCl2 was added to a...Ch. 17 - A 65.0-mL sample of 0.010 M Pb(NO3)2 was added to...Ch. 17 - How many moles of calcium chloride, CaCl2, can be...Ch. 17 - Magnesium sulfate, MgSO4, is added to 456 mL of...Ch. 17 - What is the I concentration just as AgCl begins to...Ch. 17 - What is the Cl concentration just as Ag2CrO4...Ch. 17 - Write the net ionic equation in which the slightly...Ch. 17 - Write the net ionic equation in which the slightly...Ch. 17 - Which salt would you expect to dissolve more...Ch. 17 - Which salt would you expect to dissolve more...Ch. 17 - Write the chemical equation for the formation of...Ch. 17 - Write the chemical equation for the formation of...Ch. 17 - Sufficient sodium cyanide, NaCN, was added to...Ch. 17 - The formation constant Kf for the complex ion...Ch. 17 - Prob. 17.65QPCh. 17 - Predict whether nickel(II) hydroxide, Ni(OH)2,...Ch. 17 - What is the molar solubility of CdC2O4 in 0.10 M...Ch. 17 - What is the molar solubility of ZnS in 0.10 M NH3?Ch. 17 - Prob. 17.69QPCh. 17 - Describe how you could separate the following...Ch. 17 - A student dissolved a compound in water and added...Ch. 17 - A student was asked to identify a compound. In an...Ch. 17 - Prob. 17.73QPCh. 17 - Prob. 17.74QPCh. 17 - Prob. 17.75QPCh. 17 - Prob. 17.76QPCh. 17 - For cerium(III) hydroxide, Ce(OH)3, Ksp equals 2.0...Ch. 17 - Copper(II) ferrocyanide, Cu2Fe(CN)6, dissolves to...Ch. 17 - What is the solubility of magnesium hydroxide in a...Ch. 17 - What is the solubility of silver oxide, Ag2O, in a...Ch. 17 - What is the molar solubility of Mg(OH)2 in a...Ch. 17 - What is the molar solubility of Al(OH)3 in a...Ch. 17 - Prob. 17.83QPCh. 17 - What must be the concentration of chromate ion in...Ch. 17 - A 3.20-L solution of 1.25 103 M Pb(NO3)2 is mixed...Ch. 17 - Prob. 17.86QPCh. 17 - How many grams of sodium chloride can be added to...Ch. 17 - Prob. 17.88QPCh. 17 - Prob. 17.89QPCh. 17 - Prob. 17.90QPCh. 17 - Calculate the molar solubility of silver bromide,...Ch. 17 - Prob. 17.92QPCh. 17 - The solubility of zinc oxalate, ZnC2O4, in 0.0150...Ch. 17 - The solubility of cadmium oxalate. CdC2O4, in...Ch. 17 - Prob. 17.95QPCh. 17 - Prob. 17.96QPCh. 17 - A saturated solution of copper(II) iodate in pure...Ch. 17 - A saturated solution of lead iodate in pure water...Ch. 17 - A solution contains 0.0150 M lead(II) ion. A...Ch. 17 - A solution contains 0.00740 M calcium ion. A...Ch. 17 - a If the molar solubility of cobalt(II) hydroxide...Ch. 17 - a If the molar solubility of beryllium(II)...Ch. 17 - Although silver chloride is insoluble in water, it...Ch. 17 - Crystals of AgBr can be removed from...Ch. 17 - A 1.0-L solution that is 4.2 M in ammonia is mixed...Ch. 17 - Prob. 17.106QPCh. 17 - Prob. 17.107QPCh. 17 - Prob. 17.108QPCh. 17 - Prob. 17.109QPCh. 17 - A chemist mixes 1.00 L each of 0.100 M Na2CO3 and...Ch. 17 - Prob. 17.111QPCh. 17 - Prob. 17.112QPCh. 17 - An analytical chemist has a solution containing...Ch. 17 - How would the solubility of calcium fluoride be...Ch. 17 - A scientist was interested in how soluble rust is...Ch. 17 - Prob. 17.116QPCh. 17 - Prob. 17.117QPCh. 17 - Prob. 17.118QPCh. 17 - Prob. 17.119QPCh. 17 - Suppose you add 35.6 mL of 0.578 M H2SO4 to 55.6...Ch. 17 - Prob. 17.121QPCh. 17 - Prob. 17.122QPCh. 17 - Prob. 17.123QPCh. 17 - Suppose you have a water solution that is 0.0010 M...Ch. 17 - Prob. 17.125QPCh. 17 - Suppose that an aqueous solution is in equilibrium...Ch. 17 - Prob. 17.127QPCh. 17 - The text describes zinc hydroxide as an amphoteric...Ch. 17 - A solution is 1.5 104 M Zn2 and 0.20 M HSO4. The...Ch. 17 - Prob. 17.130QPCh. 17 - What is the solubility of calcium fluoride in a...Ch. 17 - What is the solubility of magnesium fluoride in a...Ch. 17 - Prob. 17.133QPCh. 17 - Prob. 17.134QP
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- Some barium chloride is added to a solution that contains both K2SO4 (0.050 M) and Na3PO4 (0.020 M). (a) Which begins to precipitate first: the barium sulfate or the barium phosphate? (b) The concentration of the first anion species to precipitate, either the sulfate or phosphate, decreases as the precipitate forms. What is the concentration of the first species when the second begins to precipitate?arrow_forwardA solution contains 0.00740 M calcium ion. A concentrated sodium fluoride solution is added dropwise to precipitate calcium fluoride (assume no volume change). a At what concentration of F does precipitate start to form? b When [F] = 9.5 104 M, what is the calcium-ion concentration? What percentage of the calcium ion has precipitated?arrow_forwardThe concentration of barium in a saturated solution of barium sulfate at a particular temperature is 1.2 g/mL. Calculate Ksp at this temperature.arrow_forward
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- Although silver chloride is insoluble in water, it readily dissolves upon the addition of ammonia. AgCl(s)+2NH3(aq)Ag(NH3)2+(aq)+Cl(aq) a What is the equilibrium constant for this dissolving process? b Ammonia is added to a solution containing excess AgCl(s). The final volume is 1.00 L and the resulting equilibrium concentration of NH3 is 0.80 M. Calculate the number of moles of AgCl dissolved, the molar concentration of Ag(NH3)2+, and the number of moles of NH3 added to the original solution.arrow_forwardMost barium compounds are very poisonous; however, barium sulfate is often administered internally as an aid in the X-ray examination of the lower intestinal tract (Figure 15.4). This use of BaSO4 is possible because of its low solubility. Calculate the molar solubility of BaSO4 and the mass of barium present in 1.00 L of water saturated with BaSO4.arrow_forwardSolubility Equilibria Consider three hypothetical ionic solids: AX, AX2, and AX3 (each X forms X). Each of these solids has the same Ksp value, 5.5 10 7. You place 0.25 mol of each compound in a separate container and add enough water to bring the volume to 1.0 L in each case. a Write the chemical equation for each of the solids dissolving in water. b Would you expect the concentration of each solution to be 0.25 M in the compound? Explain, in some detail, why or why not. c Would you expect the concentrations of the A cations (A+, A2+, and A3+) in the three solutions to be the same? Does just knowing the stoichiometry of each reaction help you determine the answer, or do you need something else? Explain your answer in detail, but without doing any arithmetic calculations. d Of the three solids, which one would you expect to have the greatest molar solubility? Explain in detail, but without doing any arithmetic calculations. e Calculate the molar solubility of each compound.arrow_forward
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